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Simple Proline-Derived Phosphine-Thiazole Iridium Complexes for Asymmetric Hydrogenation of Trisubstituted Olefins
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - BMC.
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2013 (English)In: Asian Journal of Organic Chemistry, ISSN 2193-5807, Vol. 2, no 8, 674-680 p.Article in journal (Refereed) Published
Abstract [en]

Proline-based phosphine-thiazole/imidazole ligands have been synthesized and successfully applied in the homogeneous, iridium-catalyzed, asymmetric hydrogenation of trisubstituted functionalized and unfunctionalized olefins. Five different sets of ligands were prepared then evaluated for their catalytic activity and enantioselectivity in asymmetric hydrogenation.

Place, publisher, year, edition, pages
2013. Vol. 2, no 8, 674-680 p.
Keyword [en]
asymmetric hydrogenation, benzimidazoles, benzothiazoles, iridium, N, P-ligands
National Category
Natural Sciences
URN: urn:nbn:se:uu:diva-211044DOI: 10.1002/ajoc.201300045ISI: 000325990700009OAI: oai:DiVA.org:uu-211044DiVA: diva2:665201
Available from: 2013-11-19 Created: 2013-11-19 Last updated: 2013-11-19Bibliographically approved

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