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Iridium Catalysts with Chiral Bicyclic Pyridine-Phosphane Ligands for the Asymmetric Hydrogenation of Olefins
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - BMC.
2014 (English)In: European Journal of Organic Chemistry, ISSN 1434-193X, E-ISSN 1099-0690, Vol. 2014, no 1, p. 140-146Article in journal (Refereed) Published
Abstract [en]

New bicyclic pyridine-phosphane ligands were prepared, and their iridium complexes were evaluated in asymmetric hydrogenation of trisubstituted olefins with non-coordinating and weakly coordinating substituents. The iridium catalysts showed high reactivity and enantioselectivity for both types of olefins.

Place, publisher, year, edition, pages
2014. Vol. 2014, no 1, p. 140-146
Keywords [en]
Iridium, N, P ligands, Homogeneous catalysis, Hydrogenation, Asymmetric catalysis
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:uu:diva-216053DOI: 10.1002/ejoc.201301141ISI: 000328631700016OAI: oai:DiVA.org:uu-216053DiVA, id: diva2:689201
Available from: 2014-01-20 Created: 2014-01-17 Last updated: 2017-12-06Bibliographically approved

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