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Electronic structure of a transient histidine radical in liquid aqueous solution: EPR continuous-flow studies and density functional calculations
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Physics, Department of Quantum Chemistry.
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1999 (English)In: JOURNAL OF PHYSICAL CHEMISTRY A, ISSN 1089-5639, Vol. 103, no 9, 1283-1290 p.Article in journal (Other scientific) Published
Abstract [en]

Transient histidine radicals formed in aqueous solutions by oxidation of histidine with a Ti3+/H2O2 Fenton system at pH 2.0 have been studied by EPR using a fast continuous-flow setup and a dielectric ring resonator equipped with a mixing chamber. A histi

Place, publisher, year, edition, pages
1999. Vol. 103, no 9, 1283-1290 p.
Keyword [en]
CYTOCHROME-C PEROXIDASE; OXYGEN-EVOLVING COMPLEX; RIBONUCLEOTIDE REDUCTASE; ESCHERICHIA-COLI; TRYPTOPHAN RADICALS; ENDOR SPECTROSCOPY; EXCHANGE-ENERGY; SPIN RESONANCE; AMINO-ACIDS; IMIDAZOLE
Identifiers
URN: urn:nbn:se:uu:diva-41190OAI: oai:DiVA.org:uu-41190DiVA: diva2:69091
Note
Lassmann G, Tech Univ Berlin, Max Volmer Inst Biophys Chem & Biochem, D-10623 Berlin, Germany. Tech Univ Berlin, Max Volmer Inst Biophys Chem & Biochem, D-10623 Berlin, Germany. Univ Uppsala, Dept Quantum Chem, S-75120 Uppsala, Sweden. Univ Stockholm, DepAvailable from: 2008-10-17 Created: 2008-10-17 Last updated: 2011-01-14

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