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Tetrahydroquinoline dyes with different spacers for organic dye-sensitized solar cells.
2007 (English)In: Journal of Photochemistry and Photobiology A: Chemistry, ISSN 1010-6030, E-ISSN 1873-2666, Vol. 189, no 2-3, 295-300 p.Article in journal (Refereed) Published
Abstract [en]

Novel org. dyes (C1-1, C1-5 and C2-1) with a tetrahydroquinoline moiety as the electron donor, different thiophene-contg. electron spacers and a cyanoacrylic acid moiety as the electron acceptor have been designed and synthesized for the application in dye-sensitized solar cells (DSSCs). An interesting relationship between the dye structures, properties, and the performance of DSSCs based on these tetrahydroquinoline dyes is obtained. Although C2-1 dye, which has a rigid electron spacer, has the narrowest action spectrum among these dyes, it gives the highest solar-to-electricity conversion efficiency (η) of 4.49% (Voc = 600 mV, Jsc = 11.20 mA/cm2, ff = 0.67) of a DSSC under simulated AM 1.5 irradn. (100 mW/cm2). Under the same conditions, the η value of a DSSC based on N3 dye is 6.16%. [on SciFinder(R)]

Place, publisher, year, edition, pages
2007. Vol. 189, no 2-3, 295-300 p.
Keyword [en]
tetrahydroquinoline dye sensitizer solar cell
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:uu:diva-218499DOI: 10.1016/j.jphotochem.2007.02.018OAI: oai:DiVA.org:uu-218499DiVA: diva2:695781
Note

CAPLUS AN 2007:571397(Journal)

Available from: 2014-02-12 Created: 2014-02-12 Last updated: 2017-12-06

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Tian, Haining

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