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Atomic and Electronic Structures of Interfaces in Dye-Sensitized, Nanostructured Solar Cells
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy, Molecular and condensed matter physics.
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy, Molecular and condensed matter physics.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
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2014 (English)In: ChemPhysChem, ISSN 1439-4235, E-ISSN 1439-7641, Vol. 15, no 6, 1006-1017 p.Article, review/survey (Refereed) Published
Abstract [en]

Key processes in nanostructured dye-sensitized solar cells occur at material interfaces containing, for example, oxides, dye molecules, and hole conductors. A detailed understanding of interfacial properties is therefore important for new developments and device optimization. The implementation of X-ray-based spectroscopic methods for atomic-level understanding of such properties is reviewed. Specifically, the use of the chemical and element sensitivity of photoelectron spectroscopy, hard X-ray photoelectron spectroscopy, and resonant photoelectron spectroscopy for investigating interfacial molecular and electronic properties are described; examples include energy matching, binding configurations, and molecular orbital composition. Finally, results from the complete oxide/dye/hole-conductor systems are shown and demonstrate how the assembly itself can affect the molecular and electronic structure of the materials.

Place, publisher, year, edition, pages
2014. Vol. 15, no 6, 1006-1017 p.
Keyword [en]
dyes, pigments, interfaces, nanostructures, photoelectron spectroscopy, solar cells
National Category
Physical Chemistry Condensed Matter Physics
Identifiers
URN: urn:nbn:se:uu:diva-228203DOI: 10.1002/cphc.201301074ISI: 000334080700002OAI: oai:DiVA.org:uu-228203DiVA: diva2:733103
Available from: 2014-07-08 Created: 2014-07-07 Last updated: 2017-12-05Bibliographically approved

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Johansson, Erik M. J.Lindblad, RebeckaSiegbahn, HansHagfeldt, AndersRensmo, Håkan

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