uu.seUppsala University Publications
Change search
ReferencesLink to record
Permanent link

Direct link
In-situ probing of H2O effects on a Ru-complex adsorbed on TiO2 using high pressure XPS
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy, Molecular and condensed matter physics.
Show others and affiliations
(English)Manuscript (preprint) (Other academic)
National Category
Physical Chemistry
URN: urn:nbn:se:uu:diva-230852OAI: oai:DiVA.org:uu-230852DiVA: diva2:742133
Available from: 2014-08-31 Created: 2014-08-31 Last updated: 2016-04-20
In thesis
1. Interfaces in Dye-Sensitized Solar Cells Studied with Photoelectron Spectroscopy at Elevated Pressures
Open this publication in new window or tab >>Interfaces in Dye-Sensitized Solar Cells Studied with Photoelectron Spectroscopy at Elevated Pressures
2014 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

With an increasing demand for renewable energy sources, research efforts on different solar cell technologies are increasing rapidly. The dye-sensitized solar cell (DSC) is one such technology, taking advantage of light absorption in dye molecules. The liquid based DSC contains several interesting and important interfaces, crucial for the understanding and development of the solar cell performance. Examples of such interfaces include dye-semiconductor, electrode-electrolyte and solute-solvent interfaces. Ultimately, complete interfaces with all these components included are of particular interest. One major challenge is to understand the key functions of these systems at an atomic level and one way to achieve this is to use an element specific and surface sensitive tool, such as photoelectron spectroscopy (PES). This thesis describes the use and development of PES for studying interfaces in the DSC.

The materials part of the thesis focuses on interfaces in DSCs studied with PES and the methodology development parts focus on methods to use PES for investigations of solvated heterogeneous interfaces of interest for photoelectrochemical systems such as the DSC. More specifically, beginning with standard vacuum techniques, dye molecules bound to a semiconductor surface have been studied in terms of energy level alignment, surface coverage and binding configuration. To increase the understanding of solvation phenomena present in the liquid DSC, liquid jet experiments have been performed in close combination with theoretical quantum calculations. As a step towards an in-situ method to measure a complete, functioning (in operando) solar cell, methodology development and measurements performed with higher sample pressures are described using new high pressure X-ray photoelectron spectroscopy techniques (HPXPS).

Place, publisher, year, edition, pages
Uppsala: Acta Universitatis Upsaliensis, 2014. 75 p.
Digital Comprehensive Summaries of Uppsala Dissertations from the Faculty of Science and Technology, ISSN 1651-6214 ; 1173
Dye-sensitized solar cells, interfaces, solvation, photoelectron spectroscopy, HPXPS, HP-HAXPES, liquid jet
National Category
Physical Chemistry
Research subject
Chemistry with specialization in Physical Chemistry
urn:nbn:se:uu:diva-230855 (URN)978-91-554-9022-5 (ISBN)
Public defence
2014-10-17, Häggsalen, Ångström laboratory, Uppsala, 10:15 (English)
Available from: 2014-09-25 Created: 2014-08-31 Last updated: 2015-01-23

Open Access in DiVA

No full text

Search in DiVA

By author/editor
Eriksson K., SusannaRensmo, Håkan
By organisation
Physical ChemistryMolecular and condensed matter physics
Physical Chemistry

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Total: 296 hits
ReferencesLink to record
Permanent link

Direct link