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Reactive sputtering of NbCx-based nanocomposite coatings: An up-scaling study
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Inorganic Chemistry.
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2014 (English)In: Surface & Coatings Technology, ISSN 0257-8972, E-ISSN 1879-3347, Vol. 253, 100-108 p.Article in journal (Refereed) Published
Abstract [en]

Nanocomposite Nb-C coatings, with a C/Nb ratio of 0.93-1.59, have been deposited by reactive sputtering in a commercial sputtering system where the C is supplied from an acetylene gas at deposition rates of up to 200 nm/min. The coatings are compared to non-reactively sputtered Nb-C coatings deposited from Nb and C targets in lab-scale equipment at deposition rates two orders of magnitude lower. X-ray diffraction, X-ray photoelectron spectroscopy, and electron microscopy are used to conclude that all coatings consist of nanoctystalline Nbc(x) grains (nc-NbCx) embedded in a matrix of amorphous C (a-C). The coating performance was evaluated in terms of their mechanical, tribological, and electrical properties. The chemical stability of the coatings was evaluated by exposure to a flowing mixture of corrosive gases. It is found that the coatings have comparable microstructure and performance to the coatings deposited by non-reactive sputtering. The high deposition rate and presence of different C-radicals on the coating surface during film growth for the reactively sputtered coatings are believed to result in a smaller NbCx grain size compared to the non-reactively sputtered coatings (reactive process: 10-3 nm, non-reactive process: similar to 75-3 nm). This difference results in a thinner a-C matrix of about 0.2 nm, which is not varying with C content for the reactively sputtered coatings. The thinner a-C matrix is reflected in coating properties, with a higher conductivity and slightly higher hardness. The coating richest in C content (C/Nb ratio 1.59) shows the lowest friction (0.23), wear rate (0.17 x 10(-6) mm(3)/mN), and contact resistance before (11 m Omega at 10 N) and after (30 m Omega at 10 N) the chemical stability test. These results imply that nc-NbCx/a-C coatings of this composition are a good candidate for electrical contact applications, and that up-scaling of the process is achievable. 

Place, publisher, year, edition, pages
2014. Vol. 253, 100-108 p.
Keyword [en]
Thin film, Carbide, Electrical contacts, Contact resistance, Friction
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:uu:diva-230061DOI: 10.1016/j.surfcoat.2014.05.021ISI: 000339150200014OAI: oai:DiVA.org:uu-230061DiVA: diva2:743265
Available from: 2014-09-03 Created: 2014-08-19 Last updated: 2017-12-05Bibliographically approved

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Nedfors, NilsJansson, Ulf

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