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Palladium-Catalyzed Alkenylation of Ketone Enolates under Mild Conditions
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - BMC, Physical Organic Chemistry.
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2014 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 16, no 15, 3970-3973 p.Article in journal (Refereed) Published
Abstract [en]

A protocol for a mild, catalytic, intermolecular alkenylation of ketone enolates has been developed using a Pd/Q-Phos catalyst. Efficient intermolecular coupling of a variety of ketones with alkenyl bromides was achieved with a slight excess of LiHMDS and temperatures down to 0 degrees C.

Place, publisher, year, edition, pages
2014. Vol. 16, no 15, 3970-3973 p.
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Organic Chemistry
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URN: urn:nbn:se:uu:diva-231214DOI: 10.1021/ol5017965ISI: 000339982300031OAI: oai:DiVA.org:uu-231214DiVA: diva2:745077
Available from: 2014-09-09 Created: 2014-09-05 Last updated: 2017-12-05Bibliographically approved

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Ankner, Tobias

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