uu.seUppsala University Publications
Change search
ReferencesLink to record
Permanent link

Direct link
Structural investigation of Np2Co17 and analogue compounds under pressure
Show others and affiliations
2014 (English)In: Physical Review B. Condensed Matter and Materials Physics, ISSN 1098-0121, E-ISSN 1550-235X, Vol. 90, no 5, 054107- p.Article in journal (Refereed) Published
Abstract [en]

The structural behavior of Np2Co17 is investigated by means of high-pressure diamond-anvil compression measurements and is compared with that of the isostructural compounds Lu2Co17 and Lu2Ni17. The Th2Ni17-type hexagonal crystal structure is preserved with no measurable discontinuous volume collapses up to the highest achieved pressure, p = 43 GPa. For Np2Co17, fits to the Birch-Murnaghan and Vinet equations of state give values of the isothermal bulk modulus and its pressure derivative of B-0 = 286 GPa and B-0' = 3, revealing that this Np compound is a highly incompressible solid with stiffness comparable to that of superhard covalently bonded materials. For the Lu2T17 (T = Co, Ni) compounds, the measured bulk modulus changes from B-0 = 137 GPa for T = Co to B-0 = 257 GPa for T = Ni. The isothermal equation of state for the studied compounds are in excellent agreement with the results of ab initio fully relativistic, full-potential local spin-density functional calculations. Theoretical estimates of the bulk modulus are given also for Np2Ni17, for which B-0 is predicted to assume values intermediate between those measured for Lu2Ni17 and Np2Co17.

Place, publisher, year, edition, pages
2014. Vol. 90, no 5, 054107- p.
National Category
Physical Sciences
URN: urn:nbn:se:uu:diva-233026DOI: 10.1103/PhysRevB.90.054107ISI: 000341104300002OAI: oai:DiVA.org:uu-233026DiVA: diva2:750627
Available from: 2014-09-29 Created: 2014-09-29 Last updated: 2014-09-29Bibliographically approved

Open Access in DiVA

fulltext(1313 kB)36 downloads
File information
File name FULLTEXT01.pdfFile size 1313 kBChecksum SHA-512
Type fulltextMimetype application/pdf

Other links

Publisher's full text

Search in DiVA

By author/editor
Oppeneer, Peter M.
By organisation
Materials Theory
In the same journal
Physical Review B. Condensed Matter and Materials Physics
Physical Sciences

Search outside of DiVA

GoogleGoogle Scholar
Total: 36 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 193 hits
ReferencesLink to record
Permanent link

Direct link