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Combination of Asymmetric Supercapacitor Utilizing Activated Carbon and Nickel Oxide with Cobalt Polypyridyl-Based Dye-Sensitized Solar Cell
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2014 (English)In: Electrochimica Acta, ISSN 0013-4686, E-ISSN 1873-3859, Vol. 143, 390-397 p.Article in journal (Refereed) Published
Abstract [en]

A dye-sensitized solar cell (DSC) based on the metal-free organic sensitizer and the cobalt (II, III) polypyridyl electrolyte was integrated here within an asymmetric supercapacitor utilizing cobalt-doped nickel oxide and activated carbon as positive and negative electrodes, respectively. A low cost nickel foil served as intermediate (auxiliary) bifunctional electrode separating two parts of the device and permitting the DSC electrolyte regeneration at one side and charge storage within cobalt-doped nickel oxide at the other. The main purpose of the research was to develop an integrated photocapacitor system capable of both energy generation and its further storage. Following irradiation at the 100 mW cm(-2) level, the solar cell generated an open-circuit voltage of 0.8 V and short-circuit current of 8 mA cm(-2) which corresponds to energy conversion efficiency of 4.9%. It was further shown that upon integration with asymmetric supercapacitor, the photogenerated energy was directly injected into porous charge storage electrodes thus resulting in specific capacitance of 32 F g(-1) and energy density of 2.3 Wh kg(-1). The coulumbic and total (energy conversion and charge storage) efficiency of photocapacitor were equal to 54% and 0.6%, respectively.

Place, publisher, year, edition, pages
2014. Vol. 143, 390-397 p.
Keyword [en]
dye-sensitized solar cell, cobalt (II, III) polypyridyl redox electrolyte, asymmetric supercapacitor, nickel oxide, integrated photocapacitor
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:uu:diva-237310DOI: 10.1016/j.electacta.2014.07.125ISI: 000343626500049OAI: oai:DiVA.org:uu-237310DiVA: diva2:768065
Available from: 2014-12-03 Created: 2014-12-01 Last updated: 2017-12-05Bibliographically approved

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Haggman, LeifWang, MichaelBoschloo, GerritHagfeldt, Anders

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