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Rhodium-Catalyzed Oxidative Perfluoroalkenylation by Carbonyl Group Directed C-H Bond Activation
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - BMC.
2014 (English)In: European Journal of Organic Chemistry, ISSN 1434-193X, E-ISSN 1099-0690, no 32, 7211-7219 p.Article in journal (Refereed) Published
Abstract [en]

The selective activation of C-H bonds under mild Rh-III catalytic conditions has been developed for the perfluoroalkenylation of various cyclic and acyclic aromatic ketones. This protocol uses versatile reagents and mild conditions. It requires a very low catalyst loading and has exceptional functional group tolerance as well as provides products in good to excellent yields. An application of this approach was described for the preparation of perfluoroethyl acrylate derivatives of biologically active substances.

Place, publisher, year, edition, pages
2014. no 32, 7211-7219 p.
Keyword [en]
Homogeneous catalysis, C-H activation, Olefination, Rhodium, Regioselectivity, Fluorine
National Category
Chemical Sciences
URN: urn:nbn:se:uu:diva-238416DOI: 10.1002/ejoc.201402904ISI: 000344624000018OAI: oai:DiVA.org:uu-238416DiVA: diva2:772955
Available from: 2014-12-17 Created: 2014-12-12 Last updated: 2014-12-17Bibliographically approved

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