Functionalization of robust Zr(IV)-based metal-organic framework films via a postsynthetic ligand exchange
2015 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 51, no 1, 66-69 p.Article in journal (Refereed) Published
A facile and efficient fabrication approach for homogeneous, crack-free UiO-66 films with exceptionally high crystallinity and tunable thickness on a transparent and conductive glass substrate is reported. Two functionalized species, a catechol ligand and a Fe-2 complex with structural resemblance to the active site of [FeFe] hydrogenase, were introduced into the MOF films via a postsynthetic exchange. Voltammetric studies show the [FeFe] complex in the thinner UiO-66 films (2-5 mu m) can be reduced electrochemically.
Place, publisher, year, edition, pages
2015. Vol. 51, no 1, 66-69 p.
IdentifiersURN: urn:nbn:se:uu:diva-241388DOI: 10.1039/c4cc08218dISI: 000345909400008PubMedID: 25364799OAI: oai:DiVA.org:uu-241388DiVA: diva2:783551