A novel single-site manganese(II) complex of a pyridine derivative as a catalase mimetic for disproportionation of H2O2 in water.
2013 (English)In: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, Vol. 42, no 21, 7761-7 p.Article in journal (Refereed) Published
A novel single site Mn(II) complex was successfully synthesized and tested in the aqueous disproportionation of hydrogen peroxide. The complex was found to be stable (HR-XAS) and exhibits catalase-like activity in neutral pH. Theoretical calculations suggested a reaction mechanism involving two complexes, changes in metal oxidation state and proton shuttling.
Place, publisher, year, edition, pages
2013. Vol. 42, no 21, 7761-7 p.
IdentifiersURN: urn:nbn:se:uu:diva-252496DOI: 10.1039/c3dt50288kPubMedID: 23549197OAI: oai:DiVA.org:uu-252496DiVA: diva2:810923