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Electrochemical driven water oxidation by molecular catalysts in situ polymerized on the surface of graphite carbon electrode
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2015 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 51, no 37, p. 7883-7886Article in journal (Refereed) Published
Abstract [en]

A simple strategy to immobilize highly efficient ruthenium based molecular water-oxidation catalysts on the basal-plane pyrolytic graphite electrode (BPG) by polymerization has been demonstrated. The electrode 1@BPG has obtained a high initial turnover frequency (TOF) of 10.47 s(-1) at similar to 700 mV overpotential, and a high turnover number (TON) up to 31600 in 1 h electrolysis.

Place, publisher, year, edition, pages
2015. Vol. 51, no 37, p. 7883-7886
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Chemical Sciences
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URN: urn:nbn:se:uu:diva-253883DOI: 10.1039/c5cc00242gISI: 000353639300026PubMedID: 25854858OAI: oai:DiVA.org:uu-253883DiVA, id: diva2:816451
Available from: 2015-06-03 Created: 2015-06-03 Last updated: 2017-12-04Bibliographically approved

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Philippe, BertrandRensmo, Håkan

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