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Phosphaalkenylidene bridged Ferrocenes
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.
2012 (English)In: Journal of Organometallic Chemistry, Vol. 719, 36-40 p.Article in journal (Refereed) Published
Abstract [en]

The lithi ation of ferrocenylphosphane Fc-PH 2 (Fc = C5 H4 FeC5H 5) has been reinvestiga ted and both Fc- PHLi and Fc-PLi 2 have been identi fi ed by N MR-spectroscopy. The lithia ted phosph anide s have be en conver ted to the corresponding mono and bis(silylated) spec ies the latter of which gave synth etic access to an oligomer in wh ich three ferrocene units are symme trically connec ted by phosph aalke ne unit s. The charge distri bution within this oli gomer and its isomer s has been ana lyzed using DFT calculat ions which indicates that the iron atom of the central metal locene unit is slightly more positive than the terminal ones. The se fi nding s are sup ported exp eriment ally by Mößbauer spectroscopy and cyclic voltammetry.

Place, publisher, year, edition, pages
2012. Vol. 719, 36-40 p.
National Category
Inorganic Chemistry Organic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-254306OAI: oai:DiVA.org:uu-254306DiVA: diva2:817802
Available from: 2015-06-06 Created: 2015-06-06 Last updated: 2015-06-06

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Orthaber, Andreas

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