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Synthesis, structure and p-delocalization of a phosphaalkenyl based neutral PNP-pincer
2011 (English)In: Inorganica Chimica Acta, ISSN 0020-1693, E-ISSN 1873-3255, Vol. 374, no 1, 211-215 p.Article in journal (Refereed) Published
Abstract [en]

Preparation, characterization and structural properties of a novel bis-phosphaalkenyl based PNP-pincer are reported. In this pincer the [pi]-system is delocalized over all three donor sites, which was demonstrated with DFT calculations, UV-Vis measurements and structural findings. As a consequence of this extended delocalization the [pi]-system reveals near coplanarity which is evident from the first crystal structure for an uncomplexed bisphosphaalkenyl PNP-pincer.

Place, publisher, year, edition, pages
2011. Vol. 374, no 1, 211-215 p.
Keyword [en]
Pincer, Phosphaalkene, DFT calculations, Crystal structure
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-254302DOI: 10.1016/j.ica.2011.02.078OAI: oai:DiVA.org:uu-254302DiVA: diva2:817804
Available from: 2015-06-06 Created: 2015-06-06 Last updated: 2017-12-04

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Publisher's full texthttp://caocao.myipcn.org/science/article/B6TG5-529MVKW-5/2/ef2731585b8769f02021f7726b6e5d16

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Orthaber, Andreas

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