Synthesis, structure and p-delocalization of a phosphaalkenyl based neutral PNP-pincer
2011 (English)In: Inorganica Chimica Acta, ISSN 0020-1693, E-ISSN 1873-3255, Vol. 374, no 1, 211-215 p.Article in journal (Refereed) Published
Preparation, characterization and structural properties of a novel bis-phosphaalkenyl based PNP-pincer are reported. In this pincer the [pi]-system is delocalized over all three donor sites, which was demonstrated with DFT calculations, UV-Vis measurements and structural findings. As a consequence of this extended delocalization the [pi]-system reveals near coplanarity which is evident from the first crystal structure for an uncomplexed bisphosphaalkenyl PNP-pincer.
Place, publisher, year, edition, pages
2011. Vol. 374, no 1, 211-215 p.
Pincer, Phosphaalkene, DFT calculations, Crystal structure
IdentifiersURN: urn:nbn:se:uu:diva-254302DOI: 10.1016/j.ica.2011.02.078OAI: oai:DiVA.org:uu-254302DiVA: diva2:817804