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Recycled Poly(vinyl alcohol) Sponge for Carbon Encapsulation of Size-Tunable Tin Dioxide Nanocrystalline Composites
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Structural Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Structural Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Structural Chemistry.
2015 (English)In: ChemSusChem, ISSN 1864-5631, E-ISSN 1864-564X, Vol. 8, no 12, 2084-2092 p.Article in journal (Refereed) Published
Abstract [en]

The recycling of industrial materials could reduce their environmental impact and waste haulage fees and result in sustainable manufacturing. In this work, commercial poly(vinyl alcohol) (PVA) sponges are recycled into a macroporous carbon matrix to encapsulate size-tunable SnO2 nanocrystals as anode materials for lithium-ion batteries (LIBs) through a scalable, flash-combustion method. The hydroxyl groups present copiously in the recycled PVA sponges guarantee a uniform chemical coupling with a tin(IV) citrate complex through intermolecular hydrogen bonds. Then, a scalable, ultrafast combustion process (30s) carbonizes the PVA sponge into a 3D carbon matrix. This PVA-sponge-derived carbon could not only buffer the volume fluctuations upon the Li-Sn alloying and dealloying processes but also afford a mixed conductive network, that is, a continuous carbon framework for electrical transport and macropores for facile electrolyte percolation. The best-performing electrode based on this composite delivers a rate performance up to 9.72C (4Ag(-1)) and long-term cyclability (500cycles) for Li+ ion storage. Moreover, cyclic voltammograms demonstrate the coexistence of alloying and dealloying processes and non-diffusion-controlled pseudocapacitive behavior, which collectively contribute to the high-rate Li+ ion storage.

Place, publisher, year, edition, pages
2015. Vol. 8, no 12, 2084-2092 p.
Keyword [en]
carbon, energy storage, flash combustion, lithium, polymers
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:uu:diva-258331DOI: 10.1002/cssc.201500297ISI: 000356725300010PubMedID: 26033927OAI: oai:DiVA.org:uu-258331DiVA: diva2:841850
Funder
Swedish Foundation for Strategic Research Swedish Research Council, 2012-4681Knut and Alice Wallenberg Foundation
Available from: 2015-07-15 Created: 2015-07-13 Last updated: 2017-12-04Bibliographically approved

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Ma, YueGustafsson, TorbjörnEdstrom, Kristina

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