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Versatile Approach to 3-Phosphahexatrienes Bearing Low Coordinated Phosphorus
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.
2015 (English)In: Phosphorus Sulfur and Silicon and the Related Elements, ISSN 1042-6507, E-ISSN 1563-5325, Vol. 190, no 5-6, 638-646 p.Article in journal (Refereed) Published
Abstract [en]

lambda(3)-phosphahexatrienes were prepared from ethoxyvinyl phosphinophosphonates using the phospha-Wittig-Horner reaction. The title compounds can be easily prepared in three steps starting from dichlorophosphines with good overall yields. Although these were found to be thermally unstable, these can be trapped, for instance, with methanol. The resulting methoxyphosphines are isolated in high yields in case of aldehyde starting materials with more bulky substituents.

Place, publisher, year, edition, pages
2015. Vol. 190, no 5-6, 638-646 p.
Keyword [en]
hexatriene system, Phosphaalkene, cyclization, phospha-Wittig-Horner reaction
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-260143DOI: 10.1080/10426507.2014.983596ISI: 000357323000007OAI: oai:DiVA.org:uu-260143DiVA: diva2:846726
Available from: 2015-08-18 Created: 2015-08-17 Last updated: 2017-12-04Bibliographically approved

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Arkhypchuk, Anna I.Ott, Sascha

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