Study of the reactivity of silica supported tantalum catalysts with oxygen followed by in situ HEROS
2015 (English)In: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 17, no 28, 18262-18264 p.Article in journal (Refereed) Published
We report on the reactivity of grafted tantalum organometallic catalysts with molecular oxygen. The changes in the local Ta electronic structure were followed by in situ high-energy resolution off-resonant spectroscopy (HEROS). The results revealed agglomeration and formation of Ta dimers, which cannot be reversed. The process occurs independently of starting grafted complex.
Place, publisher, year, edition, pages
2015. Vol. 17, no 28, 18262-18264 p.
IdentifiersURN: urn:nbn:se:uu:diva-260742DOI: 10.1039/c5cp02950cISI: 000357808500003PubMedID: 26105785OAI: oai:DiVA.org:uu-260742DiVA: diva2:848316