uu.seUppsala University Publications
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Investigations on the synthesis and chemiluminescence of novel 2-coumaranones - II
Show others and affiliations
2015 (English)In: ARKIVOC, ISSN 1551-7004, E-ISSN 1551-7012, 44-59 p.Article in journal (Refereed) Published
Abstract [en]

The optimized one-pot synthesis of 16 new 2-coumaranones containing a carbamate side-chain is described. Furthermore, the quantum yields for the base-activated chemiluminescence in the presence of oxygen was determined for all compounds, with a maximum of 5.9 +/- 0.1 x 10(-2) E mol(-1), and the application of these compounds as substitutes for usual bioluminescent and chemiluminescent reagents in bioassays is anticipated. A preliminary mechanistic pathway is also suggested, making use of recent developments regarding aspects of organic chemiluminescence, in agreement with both experimental and theoretical data available on the induced 1,2-dioxetanone decomposition as well as with the high efficiency of this reaction.

Place, publisher, year, edition, pages
2015. 44-59 p.
Keyword [en]
2-Coumaranone, chemiluminescence, chemiexcitation, 1, 2-dioxetanones, alpha-peroxylactones, CIEEL, firefly bioluminescence
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:uu:diva-261329DOI: 10.3998/ark.5550190.p009.044ISI: 000358993800004OAI: oai:DiVA.org:uu-261329DiVA: diva2:850519
Available from: 2015-09-01 Created: 2015-09-01 Last updated: 2017-12-04Bibliographically approved

Open Access in DiVA

fulltext(380 kB)256 downloads
File information
File name FULLTEXT01.pdfFile size 380 kBChecksum SHA-512
750ab9710c22cf89b2c76574a701168062978a3f3e292c3b5aad989fc1150ee8831ee0ef3ff70b298ede4a5f620330d1cd3522544a2b3b192c10ee6dfd6ecce1
Type fulltextMimetype application/pdf

Other links

Publisher's full text
By organisation
Theoretical Chemistry
In the same journal
ARKIVOC
Chemical Sciences

Search outside of DiVA

GoogleGoogle Scholar
Total: 256 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 822 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf