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High-efficiency dye-sensitized solar cells with molecular copper phenanthroline as solid hole conductor
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
KTH Royal Inst Technol, Sch Chem Sci & Engn, Dept Chem, S-10044 Stockholm, Sweden..
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
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2015 (English)In: Energy & Environmental Science, ISSN 1754-5692, E-ISSN 1754-5706, Vol. 8, no 9, 2634-2637 p.Article in journal (Refereed) Published
Abstract [en]

Copper phenanthroline complexes in the solid phase can act as efficient molecular hole transporting material (HTM) for hybrid solar cells. We prepared solid-state dye-sensitized solar cells with the organic dye LEG4 and bis(2,9-dimethyl-1,10-phenanthroline)copper(I/II) (Cu(dmp)(2)) and achieved power conversion efficiencies of more than 8% under 1000 W m(-2) AM1.5G illumination, with open-circuit potentials of more than 1.0 V. The successful application of a copper-complex based HTM paves the way for low-cost and efficient hybrid solar cells, as well as for other opto-electronic devices.

Place, publisher, year, edition, pages
2015. Vol. 8, no 9, 2634-2637 p.
National Category
Energy Engineering Materials Chemistry
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URN: urn:nbn:se:uu:diva-263048DOI: 10.1039/c5ee01204jISI: 000360456600006OAI: oai:DiVA.org:uu-263048DiVA: diva2:856895
Funder
Swedish Energy AgencySwedish Research CouncilStandUp
Available from: 2015-09-25 Created: 2015-09-24 Last updated: 2017-12-01Bibliographically approved

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Sveinbjörnsson, KáriZhang, JinbaoHagfeldt, AndersBoschloo, Gerrit

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