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Magnetostructural transition in Fe5SiB2 observed with neutron diffraction
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Inorganic Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Solid State Physics.
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2016 (English)In: Journal of Solid State Chemistry, ISSN 0022-4596, E-ISSN 1095-726X, Vol. 235, 113-118 p.Article in journal (Refereed) Published
Abstract [en]

The crystal and magnetic structure of Fe5SiB2 has been studied by a combination of X-ray and neutron diffraction. Also, the magnetocrystalline anisotropy energy constant has been estimated from magnetisation measurements. High quality samples have been prepared using high temperature synthesis and subsequent heat treatment protocols. The crystal structure is tetragonal within the space group I4/mcm and the compound behaves ferromagnetically with a Curie temperature of 760 K. At 172 K a spin reorientation occurs in the compound and the magnetic moments go from aligning along the c-axis (high T) down to the ab-plane (low T). The magnetocrystalline anisotropy energy constant has been estimated to 03 MJ/m(3) at 300 K.

Place, publisher, year, edition, pages
2016. Vol. 235, 113-118 p.
National Category
Inorganic Chemistry Engineering and Technology
Identifiers
URN: urn:nbn:se:uu:diva-267572DOI: 10.1016/j.jssc.2015.12.016ISI: 000370467900017OAI: oai:DiVA.org:uu-267572DiVA: diva2:873631
Funder
Swedish Research Council
Available from: 2015-11-24 Created: 2015-11-24 Last updated: 2017-12-01Bibliographically approved
In thesis
1. Structure-Magnetism Relations in Selected Iron-based Alloys: A New Base for Rare Earth Free Magnetic Materials
Open this publication in new window or tab >>Structure-Magnetism Relations in Selected Iron-based Alloys: A New Base for Rare Earth Free Magnetic Materials
2015 (English)Licentiate thesis, comprehensive summary (Other academic)
Abstract [en]

Materials for energy applications are of great importance for a sustainable future society. Among these, stronger, lighter and more efficient magnetic materials will be able to aid mankind in many applications for energy conversion, for example generators for energy production, electric vehicles and magnetic refrigerators. Another requirement for the materials is that they should be made from cheap and abundant elements. For these reasons temperature induced magnetic transitions for three materials were studied in this work; one for permanent magnet applications and two magnetocaloric materials.

Fe5SiB2 has a high Curie temperature and orders ferromagnetically at 760 K, providing possible application as a permanent magnet material. The ordering of the magnetic moments were studied and found to be aligned along the tetragonal c-axis and Fe5SiB2 undergoes a spin transition on cooling through a transition temperature (172 K), where the spins reorient along the a-axis in an easy plane.

AlFe2B2 orders ferromagnetically at 285 K, making it a candidate for the active material in a magnetic refrigerator. The order of the magnetic transition has been studied as well as the magnetic structure. It was found that the magnetic moments are aligned along the crystallographic a-axis and that the magnetic transition is of second order.

FeMnP0.75Si0.25 undergoes a first order magnetic transition around 200 K and the transition temperatures on cooling are different for the first cooling/heating cycle than for following cycles. This so called ”virgin effect” has been studied and found to originate from an irreversible structure change on the first cooling cycle through the ferromagnetic transition temperature.

Place, publisher, year, edition, pages
Uppsala: Kph Trycksaksbolaget: Kph, 2015. 47 p.
National Category
Inorganic Chemistry
Identifiers
urn:nbn:se:uu:diva-267575 (URN)
Presentation
2015-12-17, 09:15 (English)
Opponent
Supervisors
Available from: 2015-12-02 Created: 2015-11-24 Last updated: 2015-12-02Bibliographically approved
2. Magnetic Materials for Cool Applications: Relations between Structure and Magnetism in Rare Earth Free Alloys
Open this publication in new window or tab >>Magnetic Materials for Cool Applications: Relations between Structure and Magnetism in Rare Earth Free Alloys
2017 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

New and more efficient magnetic materials for energy applications are a big necessity for sustainable future. Whether the application is energy conversion or refrigeration, materials based on sustainable elements should be used, which discards all rare earth elements. For energy conversion, permanent magnets with high magnetisation and working temperature are needed whereas for refrigeration, the entropy difference between the non-magnetised and magnetised states should be large. For this reason, magnetic materials have been synthesised with high temperature methods and structurally and magnetically characterised with the aim of making a material with potential for large scale applications. To really determine the cause of the physical properties the connections between structure (crystalline and magnetic) and, mainly, the magnetic properties have been studied thoroughly.

The materials that have been studied have all been iron based and exhibit properties with potential for the applications in mind. The first system, for permanent magnet applications, was Fe5SiB2. It was found to be unsuitable for a permanent magnet, however, an interesting magnetic behaviour was studied at low temperatures. The magnetic behaviour arose from a change in the magnetic structure which was solved by using neutron diffraction. Substitutions with phosphorus (Fe5Si1-xPxB2) and cobalt (Fe1-xCox)5PB2 were then performed to improve the permanent magnet potential. While the permanent magnetic potential was not improved with cobalt substitutions the magnetic transition temperature could be greatly controlled, a real benefit for magnetic refrigeration. For this purpose AlFe2B2 was also studied, and there it was found, conclusively, that the material undergoes a second order transition, making it unsuitable for magnetic cooling. However, the magnetic structure was solved with two different methods and was found to be ferromagnetic with all magnetic moments aligned along the crystallographic a-direction. Lastly, the origin of magnetic cooling was studied in Fe2P, and can be linked to the interactions between the magnetic and atomic vibrations.

Place, publisher, year, edition, pages
Uppsala: Acta Universitatis Upsaliensis, 2017. 70 p.
Series
Digital Comprehensive Summaries of Uppsala Dissertations from the Faculty of Science and Technology, ISSN 1651-6214 ; 1585
Keyword
Magnetism, Diffraction, X-ray scattering, Neutron Scattering, Permanent magnets, Magnetocalorics
National Category
Organic Chemistry
Research subject
Chemistry with specialization in Inorganic Chemistry
Identifiers
urn:nbn:se:uu:diva-331762 (URN)978-91-513-0123-5 (ISBN)
Public defence
2017-12-08, Häggsalen, Ångströmlaboratoriet, Lägerhyddsvägen 1, Uppsala, 09:00 (English)
Opponent
Supervisors
Available from: 2017-11-16 Created: 2017-10-20 Last updated: 2017-11-16

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Cedervall, JohanKontos, SofiaSvedlindh, PeterGunnarsson, KlasSahlberg, Martin

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