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Rapid and stereoselective C-C, C-O, C-N and C-S couplings via microwave accelerated palladium-catalyzed allylic substitutions
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2000 (English)In: Synthesis (Stuttgart), ISSN 0039-7881, E-ISSN 1437-210X, no 7, 1004-1008 p.Article in journal (Refereed) Published
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Text
Abstract [en]

Palladium-catalyzed substitution of cyclohex-2-en-1-yl ethyl carbonate with neutral C-, O-, and N-nucleophiles was achieved in 1-2 minutes using microwave flash hearing. Enantioselectivities up to 96% were observed. Ionic nucleophiles tended to result in lower ee. With S-nucleophiles problems with the stability of the nucleophile were encountered.

Place, publisher, year, edition, pages
Uppsala Univ, Uppsala Biomed Ctr, Dept Organ Pharmaceut Chem, SE-75123 Uppsala, Sweden. Royal Inst Technol, Dept Chem, SE-10044 Stockholm, Sweden., 2000. no 7, 1004-1008 p.
Keyword [en]
palladium, catalysis, enantioselective, microwave, phosphine, allylation, ligands
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-275431ISI: 000087941200019OAI: oai:DiVA.org:uu-275431DiVA: diva2:900253
Available from: 2016-02-03 Created: 2016-02-03 Last updated: 2017-11-30

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Organic Chemistry

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