uu.seUppsala University Publications
Change search
ReferencesLink to record
Permanent link

Direct link
High-speed Heck reactions in ionic liquid with controlled microwave heating
2002 (English)In: Journal of Organic Chemistry, ISSN 0022-3263, E-ISSN 1520-6904, Vol. 67, no 17, 6243-6246 p.Article in journal (Refereed) PublishedText
Abstract [en]

Palladium-catalyzed Heck arylations in the polar and robust ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate (bmimPF(6)), have for the first time been accomplished under microwave irradiation. The couplings were efficiently performed in sealed tubes within 5-45 min of heating. Without significant reductions in yield, a phosphine-free ionic catalyst phase could be recycled in five successive 20 min reactions at 180 degreesC. The product was easily removed from the reaction medium by distillation.

Place, publisher, year, edition, pages
Uppsala Univ, BMC, Dept Organ Pharmaceut Chem, SE-75123 Uppsala, Sweden., 2002. Vol. 67, no 17, 6243-6246 p.
National Category
Organic Chemistry
URN: urn:nbn:se:uu:diva-275417DOI: 10.1021/jo025942wISI: 000177559800058PubMedID: 12182671OAI: oai:DiVA.org:uu-275417DiVA: diva2:900282
Available from: 2016-02-03 Created: 2016-02-03 Last updated: 2016-02-03

Open Access in DiVA

No full text

Other links

Publisher's full textPubMed
In the same journal
Journal of Organic Chemistry
Organic Chemistry

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 26 hits
ReferencesLink to record
Permanent link

Direct link