Double core-hole states in SiX4 (X = F, Cl, Br, and CH3) molecules derived by photoelectron and KLL Auger spectroscopy
2015 (English)In: Journal of Physics, Conference Series, ISSN 1742-6588, E-ISSN 1742-6596, Vol. 635, 112057Article in journal (Refereed) PublishedText
In recent years double core-hole states are intensively studied since their chemical shifts provide detailed information about initial-state and relaxation effects in a molecule. We derived the Si 1 s(-1), 2s(-1) and 2p(-1) binding energies as well as the Si 2s(-2), 2(p-1)2p(-1), and 2p(-2) double-core hole binding energies of different SiX4 systems in order to derive the chemical shifts. Based on these results we created Wagner plots, which give insight in the initial state and the relaxation effects in the different molecules.
Place, publisher, year, edition, pages
2015. Vol. 635, 112057
IdentifiersURN: urn:nbn:se:uu:diva-279233DOI: 10.1088/1742-6596/635/11/112057ISI: 000366407000639OAI: oai:DiVA.org:uu-279233DiVA: diva2:907977
29th International Conference on Photonic, Electronic, and Atomic Collisions (ICPEAC), JUL 22-28, 2015, Toledo, SPAIN