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Studies of fullerenes by the excitation, emission, and scattering of electrons
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics.
1999 (English)In: Journal of Electron Spectroscopy and Related Phenomena, ISSN 0368-2048, E-ISSN 1873-2526, Vol. 100, no 1-3, 409-433 p.Article in journal (Refereed) Published
Abstract [en]

This paper presents an overview of how electron spectroscopies have contributed to advances in fullerene research. In particular, we illustrate the vital role these techniques have played in improving our understanding of the importance of strong electronic correlation and of electron-phonon coupling in these materials, in the derivation of electron hopping rates, in providing a direct determination of charge transfer and hybridisation in both fullerene salts and adsorbed fullerenes and in determining the optical gap of these systems. We discuss systems of increasing complexity, starting with C60 in the gas phase and in the solid state, and moving on to C60 salts and to C60 adsorbed on surfaces. Finally we look at both higher fullerenes and fullerenes with a heteroatom either on or inside the cage.

Place, publisher, year, edition, pages
1999. Vol. 100, no 1-3, 409-433 p.
Keyword [en]
energy-loss-spectroscopy, ray-absorption-spectroscopy, metal-doped C-60, ultraviolet photoelectron-spectra, solid C-60, alkali-metal, charge-transfer, band-gap, photoemission spectra, orientational disorder
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:uu:diva-66579DOI: 10.1016/S0368-2048(99)00058-4OAI: oai:DiVA.org:uu-66579DiVA: diva2:94490
Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2017-11-28Bibliographically approved

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