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Synthesis, Structure and Properties of ErNb2(OPri)13
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Materials Chemistry. Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Materials Chemistry, Inorganic Chemistry. oorganisk kemi.
2004 (English)In: Journal of Sol-Gel Science and Technology, Vol. 32, 25-29 p.Article in journal (Refereed) Published
Abstract [en]

The molecular alkoxide, ErNb2(OPri)13 was prepared by metathesis with 2KNb(OPri)6, KOPri and ErCl3, and structurally determined by single-crystal X-ray diffraction techniques. Each molecule contains a central Er3+-ion coordinates by six OPri groups placed, one via a double alkoxo-bridge and the other via a triple alkoxo.bridge. It is isostructural with LaNb2(OPri)13, in spite of the large difference in ionic radius between Er3+ and La3+ (16%). The compound was characterized by its IR- and UV-vis-NIR-spectroscopic fine structures, and found to be structurally intact in hexane:isopropanol solution.

Place, publisher, year, edition, pages
2004. Vol. 32, 25-29 p.
Keyword [en]
Er-alkoxide, IR spectroscopy, electronic spectroscopy, sol-gel precursor, structure
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-68033OAI: oai:DiVA.org:uu-68033DiVA: diva2:95944
Available from: 2006-03-21 Created: 2006-03-21 Last updated: 2011-01-12

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Westin, Gunnar

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