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Synthesis, Structure and Properties of Na2Zn(OEt)4(HOEt)5
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Materials Chemistry. Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Materials Chemistry, Inorganic Chemistry. oorganisk kemi.
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Materials Chemistry. Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Materials Chemistry, Inorganic Chemistry. oorganisk kemi.
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Materials Chemistry. Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Materials Chemistry, Inorganic Chemistry. oorganisk kemi.
2004 (English)In: Journal of Sol-Gel Science and Technology, Vol. 32, 19-23 p.Article in journal (Refereed) Published
Abstract [en]

The synthesis, structure and properties of Na2Zn(OEt)4(HOEt)5, having the right Na:Zn ratio for sol-gel synthesis of the highly Na-ion conducting ceramic Nai1.8Zn0.9Si1.1O4, is described. It was synthesised in high yield by a metathesis reaction of ZnCl2 and 4NaOEt in ethanol or ethanol/toluene solvent. The structure was determined by single-crystal X-ray methods and consists of two symmetry related polymeric strands with the metal sequence ...-Zn-Na-Na-Zn-.... Extensive hydrogen bonding is present within each chain. Further characterization was lmade with IR- and Raman-spectroscopy and thermo-calorimetry, showing that the compound is stable to 65°C.

Place, publisher, year, edition, pages
2004. Vol. 32, 19-23 p.
Keyword [en]
alkoxide, precursor, structure, synthesis
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-68235OAI: oai:DiVA.org:uu-68235DiVA: diva2:96146
Available from: 2005-02-21 Created: 2005-02-21 Last updated: 2011-01-12

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