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ORTHO-CHELATING ARENETHIOLATOCOPPER(I) COMPLEXES AS VERSATILE CATALYSTS IN THE REGIOSELECTIVE CROSS-COUPLING OF ALLYLIC DERIVATIVES WITH NBUMGI - AN EXAMPLE OF REVERSED REACTIVITY OF LEAVING GROUPS
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1995 (English)In: CHEMISTRY-A EUROPEAN JOURNAL, Vol. 1, no 6, 351-359 p.Other (Other scientific)
Abstract [en]

The regioselectivity in the arenethiolatocopper(I)-catalyzed cross-coupling reaction of allylic substrates was studied. It was found that allylic acetates gave highly gamma-selective reactions in Et(2)O at 0 degrees C with slow addition of the Grignard r

Place, publisher, year, pages
VCH PUBLISHERS INC , 1995. Vol. 1, no 6, 351-359 p.
Keyword [en]
ALLYLIC SUBSTRATES; CARBON-CARBON COUPLING; CATALYSIS; COPPER COMPOUNDS; ORGANOCOPPER REAGENTS; COPPER(I) ARENETHIOLATE; ORGANOZINC REAGENTS; MECHANISTIC ASPECTS; CONJUGATE ADDITION; GRIGNARD-REAGENTS; ALKYLATION; SN2'; STEREOCHEMISTRY; REGIOCHEMISTRY
Identifiers
URN: urn:nbn:se:uu:diva-68466OAI: oai:DiVA.org:uu-68466DiVA: diva2:96377
Note
Addresses: UNIV UPPSALA, DEPT ORGAN CHEM, S-75121 UPPSALA, SWEDEN. UNIV UTRECHT, DEBYE INST, 3584 CH UTRECHT, NETHERLANDS.Available from: 2008-10-17 Created: 2008-10-17

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