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STERIC EFFECTS IN S(N)2 REACTIONS - PRIMARY CARBON KINETIC ISOTOPE EFFECTS IN MENSHUTKIN REACTIONS
Uppsala University.
Uppsala University.
Uppsala University.
1995 (English)In: JOURNAL OF ORGANIC CHEMISTRY, Vol. 60, no 16, 5037-5040 p.Other (Other scientific)
Abstract [en]

The C-11/C-14 kinetic isotope effect (KIE) has been used to probe steric hindrance in the Menshutkin reactions of different substituted amines with labeled methyl iodide. The KIEs for the reaction of 2,6-lutidine and 2,4-lutidine with labeled methyl iodi

Place, publisher, year, pages
AMER CHEMICAL SOC , 1995. Vol. 60, no 16, 5037-5040 p.
Keyword [en]
MENSCHUTKIN-TYPE REACTION; TRANSITION-STATE; SN2 REACTION; BENZYL BENZENESULFONATES; METHYL-IODIDE; N;N-DIMETHYL-PARA-TOLUIDINE; N;N-DIMETHYLANILINES; QUATERNIZATION; NITROGEN
Identifiers
URN: urn:nbn:se:uu:diva-68703OAI: oai:DiVA.org:uu-68703DiVA: diva2:96614
Note
Addresses: UNIV UPPSALA, INST CHEM, DEPT ORGAN CHEM, S-75121 UPPSALA, SWEDEN. LUND UNIV, CTR CHEM, DIV ORGAN CHEM 1, S-22100 LUND, SWEDEN.Available from: 2008-10-17 Created: 2008-10-17

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