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THE CRYSTAL STRUCTURE OF ROOM-TEMPERATURE SYNTHESIZED ORTHORHOMBIC TLCU4SE3 FROM DIRECT-METHODS ON X-RAY-POWDER DATA
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry. Oorganisk kemi.
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry. Oorganisk kemi.
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry. Oorganisk kemi.
1995 (English)In: J Alloys Comp, Vol. 224, 171-176 p.Article in journal (Refereed) Published
Abstract [en]

An orthorhombic modification of TlCu4Se3 was synthesised at room temperature by oxidative copper extraction from TlCu5Se3. It crystallises in a new structure type, space group Pnnm, with the cell parameters a = 12.4306(2) Angstrom, b = 12.7997(2) Angstrom, c= 3.93516(6) Angstrom. The structure is closely related to the tetragonal structure of the parent compound.

Place, publisher, year, edition, pages
1995. Vol. 224, 171-176 p.
Keyword [en]
X-RAY POWDER DATA; METALLIC CONDUCTORS; TRANSFORMATION MECHANISMS; STRUCTURE REFINEMENT; METAL; SYSTEM; KCU4S3
Identifiers
URN: urn:nbn:se:uu:diva-68724OAI: oai:DiVA.org:uu-68724DiVA: diva2:96635
Note
Addresses: BERGER R, UPPSALA UNIV, DEPT Materials Chem, BOX 538, S-75121 UPPSALA, SWEDEN. UNIV STOCKHOLM, DEPT STRUCT CHEM, S-10691 STOCKHOLM, SWEDEN.Available from: 2006-11-08 Created: 2006-11-08 Last updated: 2011-01-16

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