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DIHYDROQUINIDINE CONFORMATION REVISITED - VARIABLE-TEMPERATURE NMR AND CD SPECTROSCOPY, AND MOLECULAR MECHANICS COMPUTATIONS
Uppsala University.
Uppsala University.
Uppsala University.
1995 (English)In: TETRAHEDRON LETTERS, Vol. 36, no 12, 2137-2140 p.Other (Other scientific)
Abstract [en]

Combination of variable temperature NMR and CD spectroscopy, and molecular mechanics computations shows that dihydroquinidine exists in two conformations, anti,open (80-90%) and syn,closed (10-20%) separated by a barrier of 8.3 kcal/mol in ether solution

Place, publisher, year, pages
PERGAMON-ELSEVIER SCIENCE LTD , 1995. Vol. 36, no 12, 2137-2140 p.
Keyword [en]
CINCHONA ALKALOIDS
Identifiers
URN: urn:nbn:se:uu:diva-69009OAI: oai:DiVA.org:uu-69009DiVA: diva2:96920
Note
Addresses: BERG U, LUND UNIV, CTR CHEM, POB 124, S-22100 LUND, SWEDEN. UNIV UPPSALA, INST CHEM, S-75121 UPPSALA, SWEDEN.Available from: 2008-10-17 Created: 2008-10-17

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