Solvent Dependence of Enantioselectivity for a Base Catalyzed 1,3-Hydron Transfer Reaction: A Kinetic Isotope Effect and NMR Spectroscopic Study.
1995 (English)Other (Other academic)
The base-catalyzed rearrangement of 1-methylindene (1) to 3-methylindene (2) has been studied. The reaction proceeds with substrate enantioselectivity (kinetic resolution) when chiral tertiary amines are used as catalysts. When dihydroquinidine (DHQD) (3
Place, publisher, year, edition, pages
AMER CHEMICAL SOC , 1995. Vol. 60, no 5, 1356-1364 p.
IdentifiersURN: urn:nbn:se:uu:diva-69099DOI: 10.1021/jo00111a050OAI: oai:DiVA.org:uu-69099DiVA: diva2:97010
Addresses: UNIV UPPSALA, INST CHEM, S-75121 UPPSALA, SWEDEN.2008-10-172008-10-172011-01-08