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Solvent Dependence of Enantioselectivity for a Base Catalyzed 1,3-Hydron Transfer Reaction: A Kinetic Isotope Effect and NMR Spectroscopic Study.
Uppsala University.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry.ORCID iD: 0000-0002-9092-261
Uppsala University.
1995 (English)In: Journal of Organic Chemistry, ISSN 0022-3263, E-ISSN 1520-6904, Vol. 60, no 5, 1356-1364 p.1356-1364 p.Article in journal (Refereed) Published
Abstract [en]

The base-catalyzed rearrangement of 1-methylindene (1) to 3-methylindene (2) has been studied. The reaction proceeds with substrate enantioselectivity (kinetic resolution) when chiral tertiary amines are used as catalysts. When dihydroquinidine (DHQD) (3

Place, publisher, year, edition, pages
American Chemical Society (ACS), 1995. Vol. 60, no 5, 1356-1364 p.1356-1364 p.
National Category
Organic Chemistry
Research subject
Chemistry with specialization in Organic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-69099DOI: 10.1021/jo00111a050OAI: oai:DiVA.org:uu-69099DiVA: diva2:97010
Note

Addresses: UNIV UPPSALA, INST CHEM, S-75121 UPPSALA, SWEDEN.

Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2017-06-12

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Gogoll, AdolfMatsson, Olle

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