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The crystal structure of 2-[N,N-dimethylamino)methyl] benzenetellurenyl chloride
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry. Department of Biochemistry and Organic Chemistry, Organic Chemistry I. Organisk kemi.
2004 (English)In: Phosphorus, Sulfur, and Silicon, ISSN 1042-6507, Vol. 179, 285-292 p.Article in journal (Refereed) Published
Abstract [en]

The crystal structure of 2-[(N,N-dimethylamino)methyl]benzenetellurenyl chloride (2), a compound previously formulated as bis [[2-(N,N-dimethylamino)methyl]phenyl] ditelluride bis hydrochloride (1a), was determinded. In the molecule 2, tellurium is bonded to the carbon of the phenyl group [2.120(3)Å], the nitrogen o fthe ortho dimethylamino substituent [2.362(3)Å], and the chlorine atom [2.536[1]Å]. There also is an intermolecular interaction of the tellurium atom with the phenyl ring of a neighbouring molecule [3.655(1)Å], resulting in the formation of zigzag chains along the b axis. The noncentorsymmetric space group of the crystal can be explained by the chiral surrounding of tellurium.

Place, publisher, year, edition, pages
2004. Vol. 179, 285-292 p.
Keyword [en]
Conformation, crystal structure, telluroorganic compounds
National Category
Organic Chemistry
URN: urn:nbn:se:uu:diva-69392DOI: doi:10.1080/10426500490262289OAI: oai:DiVA.org:uu-69392DiVA: diva2:97303
Available from: 2005-03-31 Created: 2005-03-31 Last updated: 2011-01-12

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