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Synthesis of a Ru(bpy)(3)-type complex linked to a free terpyridine ligand and its use for preparation of polynuclear bimetallic complexes
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry, Analytical Chemistry.
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2004 (English)In: Catalysis Today, ISSN 0920-5861, E-ISSN 1873-4308, Vol. 98, no 4, 529-536 p.Article in journal (Refereed) Published
Abstract [en]

A terpyridine ligand has been covalently linked to a Ru(bpy)3 complex via an amide bond. By using this functionalized terpyridine ligand, a series of multinuclear bimetallic complexes have been synthesized and characterized. One of these complexes has the structure of di-μ-oxo-bridged Mn dimer. EPR spectra of this complex showed that, depending on the procedure for the preparation, the oxidation states of the Mn dimer is either a Mn2III,IV dimer or a mixture of this and Mn2IV,IV dimer. Water oxidation catalyzed by this complex has been performed.

Place, publisher, year, edition, pages
2004. Vol. 98, no 4, 529-536 p.
Keyword [en]
water oxidation, artificial photosynthesis, photosystem II, ruthenium-manganese, electrochemistry, EPR, homogeneous catalysis
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:uu:diva-69413DOI: 10.1016/j.cattod.2004.09.008OAI: oai:DiVA.org:uu-69413DiVA: diva2:97324
Available from: 2005-05-24 Created: 2005-05-24 Last updated: 2017-11-21Bibliographically approved

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Bergquist, Jonas

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