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Ruthenium-catalyzed Oppenauer-type oxidation of 3 beta-hydroxy steroids. A highly efficient entry into the steroidal hormones with 4-en-3-one functionality
Uppsala University.
Uppsala University.
Uppsala University.
1996 (English)In: JOURNAL OF ORGANIC CHEMISTRY, Vol. 61, no 19, 6587-6590 p.Other (Other scientific)
Abstract [en]

Oxidation of 5-unsaturated 3 beta-hydroxy steroids 1 to the corresponding 4-en-3-one derivatives 2 can be performed efficiently by acetone at reflux in the presence of a catalytic system consisting of either (PPh(3))(3)RuCl2 (3) and K2CO3 or [(C(4)Ph(4)C

Place, publisher, year, edition, pages
AMER CHEMICAL SOC , 1996. Vol. 61, no 19, 6587-6590 p.
Keyword [en]
URN: urn:nbn:se:uu:diva-69564OAI: oai:DiVA.org:uu-69564DiVA: diva2:97475
Addresses: Almeida MLS, UNIV UPPSALA, DEPT ORGAN CHEM, BOX 531, S-75121 UPPSALA, SWEDEN. UNIV LEICESTER, DEPT CHEM, LEICESTER LE1 7RH, LEICS, ENGLAND.Available from: 2008-10-17 Created: 2008-10-17

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