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Effects of beta-substituents and ancillary ligands on the structure and stability of (eta(3)-allyl)palladium complexes. Implications for the regioselectivity in nucleophilic addition reactions
Uppsala University.
1996 (English)In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Vol. 118, no 33, 7818-7826 p.Other (Other scientific)
Abstract [en]

(eta(3)-Allyl)palladium complexes possessing various allylic beta-substituents (X = Cl, OCH3, H) and ancillary ligands on palladium (L = Cl-, F-, PH3) have been studied at the second-order Moller-Plesset (MP2) and fourth-order Moller-Plesset (MP4) pertur

Place, publisher, year, pages
AMER CHEMICAL SOC , 1996. Vol. 118, no 33, 7818-7826 p.
Keyword [en]
PALLADIUM-CATALYZED 1;4-ADDITION; PI-ALLYLPALLADIUM COMPLEXES; EFFECTIVE CORE POTENTIALS; ALLYLIC SUBSTITUTION; CONJUGATED DIENES; TRANSITION-METAL; (PI-ALLYL)PALLADIUM COMPLEXES; MOLECULAR CALCULATIONS; ETA-3-ALLYL COMPLEXES; ROTATIONAL BARRIERS
Identifiers
URN: urn:nbn:se:uu:diva-69586OAI: oai:DiVA.org:uu-69586DiVA: diva2:97497
Note
Addresses: Szabo KJ, UNIV UPPSALA, DEPT ORGAN CHEM, BOX 531, S-75121 UPPSALA, SWEDEN.Available from: 2008-10-17 Created: 2008-10-17

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