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Using incoming group C-11/C-14 kinetic isotope effects to model the transition states for the S(N)2 reactions between para-substituted benzyl chlorides and labeled cyanide ion
Uppsala University.
Uppsala University.
Uppsala University.
Uppsala University.
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1996 (English)In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Vol. 118, no 27, 6350-6354 p.Other (Other scientific)
Abstract [en]

A large incoming group C-11/C-14 kinetic isotope effect of 1.0104 +/- 0.0023 has been measured for the S(N)2 reaction between benzyl chloride and labeled cyanide ion in 20% aqueous DMSO at 30.00 degrees C. These large incoming group kinetic isotope effec

Place, publisher, year, pages
AMER CHEMICAL SOC , 1996. Vol. 118, no 27, 6350-6354 p.
Keyword [en]
METHYL-TRANSFER; DEUTERIUM; NITROGEN
Identifiers
URN: urn:nbn:se:uu:diva-69653OAI: oai:DiVA.org:uu-69653DiVA: diva2:97564
Note
Addresses: Matsson O, UNIV UPPSALA, INST CHEM, DEPT ORGAN CHEM, BOX 531, S-75121 UPPSALA, SWEDEN. LAURENTIAN UNIV, DEPT CHEM & BIOCHEM, SUDBURY, ON P3E 2C6, CANADA.Available from: 2008-10-17 Created: 2008-10-17

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