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Syntheses of theaspirone and vitispirane via palladium(II)-catalyzed oxaspirocyclization
Uppsala University.
Uppsala University.
Uppsala University.
Uppsala University.
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1996 (English)In: JOURNAL OF ORGANIC CHEMISTRY, Vol. 61, no 5, 1825-1829 p.Other (Other scientific)
Abstract [en]

Total syntheses of theaspirone (A and B) and vitispirane (A and B) are described. The key step in the syntheses is the palladium(II)-catalyzed intramolecular oxaspirocyclization of diene alcohol 4 to either vitispirane or the allylic alcohol 9. The outco

Place, publisher, year, pages
AMER CHEMICAL SOC , 1996. Vol. 61, no 5, 1825-1829 p.
Keyword [en]
STEREOCONTROLLED LACTONIZATION REACTIONS; PALLADIUM-CATALYZED 1;4-ADDITION; CONJUGATED DIENES; VOLATILE COMPONENTS; REDUCTION; CONSTITUENTS; NUCLEOPHILES; PRECURSORS; HYDRIDE; KETONES
Identifiers
URN: urn:nbn:se:uu:diva-70009OAI: oai:DiVA.org:uu-70009DiVA: diva2:97920
Note
Addresses: UNIV UPPSALA, DEPT ORGAN CHEM, S-75121 UPPSALA, SWEDEN. FAC SCI & TECHNIQUES NANTES, CNRS, SYNTH ORGAN LAB, F-44072 NANTES 03, FRANCE.Available from: 2008-10-17 Created: 2008-10-17

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