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Aerobic oxidations on metal macrocycles encapsulated in zeolites
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Biochemistry and Organic Chemistry, Organic Chemistry.
1995 (English)In: Studies in Surface Science and Catalysis, ISSN 0167-2991, Vol. 94, 728-735 p.728-735 p.Article in journal, Meeting abstract (Refereed) Published
Abstract [en]

Zeolite-encapsulated Fe-phthalocyanine and Co-salophen catalysts were used in the palladium-catalyzed aerobic oxidation of hydroquinone to benzoquinone, in the oxidation of l-octene to 2-octanone and in the allylic oxidation of cyclohexene to 3-acetoxycyclohexene. These catalysts proved to be active in the above reactions and they were stable towards self-oxidation and it was possible to reuse them in subsequent runs. The specific activity of the encapsulated Fe-phthalocyanine catalyst was about four times higher than those of the free complex.

Place, publisher, year, edition, pages
1995. Vol. 94, 728-735 p.728-735 p.
National Category
Natural Sciences
URN: urn:nbn:se:uu:diva-70082DOI: 10.1016/S0167-2991(06)81290-5OAI: oai:DiVA.org:uu-70082DiVA: diva2:97993
Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2013-10-03Bibliographically approved

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