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Synthesis of a Ru(bpy)3-type complex linked to a free terpyridine ligand and its use for preparation of polynuclear bimetallic complexes
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry. Analytisk kemi.
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2004 (English)In: Catalysis Today, no 98, 529-536 p.Article in journal (Refereed) Published
Abstract [en]

A terpyridine ligand has been covalently linked to a Ru(bpy)3 complex via an amide bond. By using this functionalized terpyridine ligand, a series of multinuclear bimetallic complexes have been synthesized and characterized. One of these complexes has the structure of di-u-oxo-bridged Mn dimer. EPR spectra of this complex showed that, depending on the procedure for the preparation, the oxidation states of the Mn dimer is either a Mn2 III,IV dimer or a mixture of this and Mn2 IV,IV dimer. Water oxidation catalyzed by this complex has been performed.

Place, publisher, year, edition, pages
2004. no 98, 529-536 p.
Keyword [en]
Water oxidation, Artificial photosynthesis, Photosystem II, Ruthenium-manganese, EPR, Homogeneous catalysis
URN: urn:nbn:se:uu:diva-70730OAI: oai:DiVA.org:uu-70730DiVA: diva2:98641
Available from: 2005-04-27 Created: 2005-04-27 Last updated: 2011-01-12

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Bergquist, Jonas
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