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  • 1.
    Agrios, Alexander G.
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Low-temperature TiO2 Films for Dye-sensitized Solar Cells: Factors Affecting Energy Conversion Efficiency2008In: The Journal of Physical Chemistry C, ISSN 1932-7447, E-ISSN 1932-7455, Vol. 112, no 27, p. 10021-10026Article in journal (Refereed)
    Abstract [en]

    Semiconductor films prepd. by electrostatic layer-by-layer deposition can be used to fabricate dye-sensitized solar cells after low-temp. treatment (150 DegC). However, the resulting photocurrent is much less than when the film is sintered at 500 DegC. The difference in short-circuit current is a factor of 2.2 with the Ru-based dye N719 and is 3.5 with the org. dye D5. The photocurrent at a given wavelength is proportional to the light-harvesting efficiency, charge injection effciency, and charge collection efficiency. Sintered films take up more than 60% more of either dye than unsintered films and therefore absorb more photons. Electron injection is hindered in unsintered films due to a conduction band edge potential 100 mV more neg. than in a sintered electrode. Addnl. injection effects could be due to adsorption of the dye to polymer rather than to TiO2 in unsintered films, although our measurements were inconclusive on this point. Kinetic studies show electron transport times (ttr) an order of magnitude faster then electron lifetimes (te) in both sintered and unsintered electrodes. Furthermore, a Li+ insertion expt. shows that both films have good elec. connectivity between TiO2 nanoparticles. Unsintered films thus exhibit efficient charge transport despite the presence of polymer and the lack of heat treatment to induce necking.

  • 2.
    Aitola, Kerttu
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Halme, Janne
    Feldt, Sandra
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Lohse, Peter
    Borghei, Maryam
    Kaskela, Antti
    Nasibulin, Albert G.
    Kauppinen, Esko I.
    Lund, Peter D.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Highly catalytic carbon nanotube counter electrode on plastic for dye solar cells utilizing cobalt-based redox mediator2013In: Electrochimica Acta, ISSN 0013-4686, E-ISSN 1873-3859, Vol. 111, p. 206-209Article in journal (Refereed)
    Abstract [en]

    A flexible, slightly transparent and metal-free random network of single-walled carbon nanotubes (SWCNTs) on plain polyethylene terephthalate (PET) plastic substrate outperformed platinum on conductive glass and on plastic as the counter electrode (CE) of a dye solar cell employing a Co(II/III)tris(2,2'-bipyridyl) complex redox mediator in 3-methoxypropionitrile solvent. The CE charge-transfer resistance of the SWCNT film was 0.60 Omega cm(2), 4.0 Omega cm(2) for sputtered platinum on indium tin oxide-PET substrate and 1.7 Omega cm(2) for thermally deposited Pt on fluorine-doped tin oxide glass, respectively. The solar cell efficiencies were in the same range, thus proving that an entirely carbon-based SWCNT film on plastic is as good CE candidate for the Co electrolyte. (C) 2013 Elsevier Ltd. All rights reserved.

  • 3.
    Aitola, Kerttu
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Sveinbjörnsson, Kári
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Correa-Baena, Juan-Pablo
    Ecole Polytech Fed Lausanne, Lab Photomol Sci, EPFL SB ISIC LSPM, CH G1 523,Chemin Alamb,Stn 6, CH-1015 Lausanne, Switzerland..
    Kaskela, Antti
    Aalto Univ, Sch Sci, Dept Appl Phys, POB 15100, FI-00076 Aalto, Finland..
    Abate, Antonio
    Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, EPFL SB ISIC LPI, CH G1 526,Stn 6, CH-1015 Lausanne, Switzerland..
    Tian, Ying
    Aalto Univ, Sch Sci, Dept Appl Phys, POB 15100, FI-00076 Aalto, Finland..
    Johansson, Erik M. J.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Graetzel, Michael
    Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, Inst Chem Sci & Engn, EPFL SB ISIC LPI, CH G1 526,Stn 6, CH-1015 Lausanne, Switzerland..
    Kauppinen, Esko I.
    Aalto Univ, Sch Sci, Dept Appl Phys, POB 15100, FI-00076 Aalto, Finland..
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry. Ecole Polytech Fed Lausanne, Lab Photomol Sci, EPFL SB ISIC LSPM, CH G1 523,Chemin Alamb,Stn 6, CH-1015 Lausanne, Switzerland..
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Carbon nanotube-based hybrid hole-transporting material and selective contact for high efficiency perovskite solar cells2016In: Energy & Environmental Science, ISSN 1754-5692, E-ISSN 1754-5706, Vol. 9, no 2, p. 461-466Article in journal (Refereed)
    Abstract [en]

    We demonstrate a high efficiency perovskite solar cell with a hybrid hole-transporting material-counter electrode based on a thin single-walled carbon nanotube (SWCNT) film and a drop-cast 2,2,7,-7-tetrakis(N, N-di-p-methoxyphenylamine)-9,90-spirobifluorene (Spiro-OMeTAD) hole-transporting material (HTM). The average efficiency of the solar cells was 13.6%, with the record cell yielding 15.5% efficiency. The efficiency of the reference solar cells with spin-coated Spiro-OMeTAD hole-transportingmaterials (HTMs) and an evaporated gold counter electrode was 17.7% (record 18.8%), that of the cells with only a SWCNT counter electrode (CE) without additional HTM was 9.1% (record 11%) and that of the cells with gold deposited directly on the perovskite layer was 5% (record 6.3%). Our results show that it is possible to manufacture high efficiency perovskite solar cells with thin film (thickness less than 1 mu m) completely carbon-based HTMCEs using industrially upscalable manufacturing methods, such as press-transferred CEs and drop-cast HTMs.

  • 4.
    Aitola, Kerttu
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Zhang, Jinbao
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Vlachopoulos, Nick
    Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn, SB ISIC LSPM, CH-1015 Lausanne, Switzerland..
    Halme, Janne
    Aalto Univ, Sch Sci, Dept Appl Phys, Aalto 00076, Finland..
    Kaskela, Antti
    Aalto Univ, Sch Sci, Dept Appl Phys, Aalto 00076, Finland..
    Nasibulin, Albert G.
    Aalto Univ, Sch Sci, Dept Appl Phys, Aalto 00076, Finland.;Skolkovo Inst Sci & Technol, Skolkovo, Russia..
    Kauppinen, Esko I.
    Aalto Univ, Sch Sci, Dept Appl Phys, Aalto 00076, Finland..
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Carbon nanotube film replacing silver in high-efficiency solid-state dye solar cells employing polymer hole conductor2015In: Journal of Solid State Electrochemistry, ISSN 1432-8488, E-ISSN 1433-0768, Vol. 19, no 10, p. 3139-3144Article in journal (Refereed)
    Abstract [en]

    A semitransparent, flexible single-walled carbon nanotube (SWCNT) film was efficiently used in place of evaporated silver as the counter electrode of a poly(3,4-ethylenedioxythiophene) polymer-based solid-state dye solar cell (SSDSC): the solar-to-electrical energy conversion efficiency of the SWCNT-SSDSC was 4.8 % when it was 5.2 % for the Ag-SSDSC. The efficiency difference stemmed from a 0.1-V difference in the open-circuit voltage, whose reason was speculated to be related to the different recombination processes in the two types of SSDSCs.

  • 5. Alarcón, H.
    et al.
    Hedlund, Maria
    Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics, Physics I.
    Johansson, Erik M. J.
    Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics, Physics I.
    Rensmo, Håkan
    Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics, Physics I.
    Hagfeldt, Anders
    KTH, Fysikalisk kemi / Physical Chemistry.
    Boschloo, Gerrit K.
    KTH, Fysikalisk kemi / Physical Chemistry.
    Modification of nanostructured TiO2 electrodes by electrochemical Al3+ insertion: Effects on dye-sensitized solar cell performance2007In: The Journal of Physical Chemistry C, ISSN 1932-7447, E-ISSN 1932-7455, Vol. 111, no 35, p. 13267-13274Article in journal (Refereed)
    Abstract [en]

    Nanostructured TiO2 films were modified by insertion with aluminum ions using an electrochemical process. After heat treatment these films were found suitable as electrodes in dye-sensitized solar cells. By means of a catechol adsorption test, as well as photoelectron spectroscopy (PES), it was demonstrated that the density of Ti atoms at the metal oxide/electrolyte interface is reduced after Al modification. There is, however, not a complete coverage of aluminum oxide onto the TiO2, but the results rather suggest either the formation of a mixed Al−Ti oxide surface layer or formation of a partial aluminum oxide coating. No new phase could, however, be detected. In solar cells incorporating Al-modified TiO2 electrodes, both electron lifetimes and electron transport times were increased. At high concentrations of inserted aluminum ions, the quantum efficiency for electron injection was significantly decreased. Results are discussed at the hand of different models:  A multiple trapping model, which can explain slower kinetics by the creation of additional traps during Al insertion, and a surface layer model, which can explain the reduced recombination rate, as well as the reduced injection efficiency, by the formation of a blocking layer.

  • 6.
    Aranyos, V
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry.
    Grennberg, Helena
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Tingry, S
    Lindquist, Sten-Eric
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Electrochemical and photoelectrochemical investigation of new carboxylatobipyridine (bis-bipyridine)ruthenium(II) complexes for dye-sensitized TiO2 electrodes2000In: SOLAR ENERGY MATERIALS AND SOLAR CELLS, ISSN 0927-0248, Vol. 64, no 2, p. 97-114Article in journal (Refereed)
    Abstract [en]

    Methods for the preparation and purification of new carboxylated 2,2'-bipyridine ligands, two of which contain the new anchoring functionality malonate, and a reliable method for the synthesis of the corresponding [Ru(bpy)(2)(L)](PF6)(2) complexes are des

  • 7.
    Aranyos, Viviane
    et al.
    Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Physical Chemistry. Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry I.
    Hagfeldt, Anders
    Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Physical Chemistry. Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry I.
    Grennberg, Helena
    Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry. Organisk kemi.
    Figgemeier, Egbert
    Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Physical Chemistry.
    Electropolymerisable bipyridine ruthenium(II) complexes: synthesis, spectroscopic and electrochemical characterisation of 4-((2-thienyl)ethenyl)-and 4,4'-di((2-thienyl) ethenyl)-2,2'-bipyridine ruthenium complexes2004In: Polyhedron, Vol. 23, p. 589-598Article in journal (Refereed)
    Abstract [en]

    Four new ruthenium polypyridyl complexes with mono- or di-((2-thienyl) ethenyl) substituted bipyridines have been synthesized. The complexes were characterized by NMR, elemental analysis, UV-Vis absorption and electrochemistry (differentioal pulse and cyclic voltammetry). Electroactive polymer films of these complexes have been prepared by oxidative electropolymerisation and characterized by UV-Vis absorption spectroscopy and electrochemistry. The electrochemically induced polymerisation of the complexes resulted in a significant shift of the oxidation potential of the Ru(II)-Ru(III) process towards more positive potentials. Also, MLCT absorption band of the polymeric complexes is shifted towards shorter wavelengths. These results are interpreted in terms of an interrupiton of the conjugated system of the (2-thienyl)ethenyl-substituted bipyridine ligands due to a radical polymerisation mechanism affecting rather the ethenyl part of the ligand than the thienyl.

  • 8. Aranyos, Viviane
    et al.
    Hjelm, Johan
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Hagfeldt, Anders
    Grennberg, Helena
    Electropolymerisable bipyridine ruthenium(II) complexes. Synthesis and electrochemical characterisation of 4-(3-methoxystyryl)- and 4,4'-di(3-methoxystyryl)-2,2'-bipyridine ruthenium complexes2001In: Journal of the Chemical Society - Dalton Transactions, ISSN 1472-7773, no 8, p. 1319-1325Article in journal (Refereed)
  • 9.
    Aranyos, Viviane
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry.
    Hjelm, Johan
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Grennberg, Helena
    Free-base tetra-arylphthalocyanines for dye-sensitised nanostructured solar cell applications2001In: JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, ISSN 1088-4246, Vol. 5, no 8, p. 609-616Article in journal (Refereed)
    Abstract [en]

    Adsorption of phthalocyanines lacking conventional attaching substituents onto nanostructured TiO2 electrodes has been studied, and some of the important factors for sensitisation have been identified. Tetra-dimethoxyphenyl phthalocyanine (2) and tetra-ph

  • 10.
    Aranyos, Viviane
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Hjelm, Johan
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Grennberg, Helena
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry.
    Tuning the properties of ruthenium bipyridine dyes for solar cells by substitution on the ligands – characterisation of bis[4,4’-di(2-(3-methoxyphenyl)ethenyl)-2,2’-bipyridine][4,4’-dicarboxy-2,2’-bipyridine]ruthenium(II) dihexafluorophosphate2003In: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, p. 1280-1283Article in journal (Refereed)
  • 11. Awais, Muhammad
    et al.
    Gibson, Elizabeth
    Vos, Johannes G.
    Dowling, Denis P.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Dini, Danilo
    Fabrication of Efficient NiO Photocathodes Prepared via RDS with Novel Routes of Substrate Processing for p-Type Dye-Sensitized Solar Cells2014In: CHEMELECTROCHEM, ISSN 2196-0216, Vol. 1, no 2, p. 384-391Article in journal (Refereed)
    Abstract [en]

    p-type dye sensitized solar cells (p-DSCs) derived from nickel oxide (NiO) photocathodes have been obtained via rapid discharge sintering (RDS) of parent metal oxide nanoparticles deposited onto differently treated substrates utilizing a plasma atmosphere with microwave radiation as heat source. This method produces NiO thin films (0.6 < l < 6 mu m) with mesoporous features and large surface areas as required for efficient dye-loading and high photocurrents. Erythrosine B (ERY) was used to sensitize the oxide in the visible spectrum. We have analyzed and compared the photoelectrochemical performances of the p-DSCs assembled with the various types of NiO samples prepared by RDS techniques with different treatments of the supporting substrate prior to, or during, spray deposition of the NiO nanoparticles. The best photovoltaic performances were obtained when the transparent conducting substrate (TCS) was heated during spraying. We believe that this is because the charge transfer through the NiO film and the charge collection at the TCS/NiO film interface were the most efficient with this sample. To our knowledge, the photovoltaic performances reported here are the best achieved with the commercial dye ERY as sensitizer.

  • 12. Bagheri, Narjes
    et al.
    Aghaei, Alireza
    Ghotbi, Mohammad Yeganeh
    Marzbanrad, Ehsan
    Vlachopoulos, Nick
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Haggman, Leif
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Wang, Michael
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Skunik-Nuckowska, Magdalena
    Kulesza, Pawel. J.
    Combination of Asymmetric Supercapacitor Utilizing Activated Carbon and Nickel Oxide with Cobalt Polypyridyl-Based Dye-Sensitized Solar Cell2014In: Electrochimica Acta, ISSN 0013-4686, E-ISSN 1873-3859, Vol. 143, p. 390-397Article in journal (Refereed)
    Abstract [en]

    A dye-sensitized solar cell (DSC) based on the metal-free organic sensitizer and the cobalt (II, III) polypyridyl electrolyte was integrated here within an asymmetric supercapacitor utilizing cobalt-doped nickel oxide and activated carbon as positive and negative electrodes, respectively. A low cost nickel foil served as intermediate (auxiliary) bifunctional electrode separating two parts of the device and permitting the DSC electrolyte regeneration at one side and charge storage within cobalt-doped nickel oxide at the other. The main purpose of the research was to develop an integrated photocapacitor system capable of both energy generation and its further storage. Following irradiation at the 100 mW cm(-2) level, the solar cell generated an open-circuit voltage of 0.8 V and short-circuit current of 8 mA cm(-2) which corresponds to energy conversion efficiency of 4.9%. It was further shown that upon integration with asymmetric supercapacitor, the photogenerated energy was directly injected into porous charge storage electrodes thus resulting in specific capacitance of 32 F g(-1) and energy density of 2.3 Wh kg(-1). The coulumbic and total (energy conversion and charge storage) efficiency of photocapacitor were equal to 54% and 0.6%, respectively.

  • 13.
    Bagheri, Narjes
    et al.
    Mat & Energy Res Ctr, Div Ceram, POB 31787-316, Karaj, Iran..
    Aghaei, Alireza
    Mat & Energy Res Ctr, Div Ceram, POB 31787-316, Karaj, Iran..
    Vlachopoulos, Nick
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Skunik-Nuckowska, Magdalena
    Univ Warsaw, Fac Chem, Pasteura 1, PL-02093 Warsaw, Poland..
    Kulesza, Pawel J.
    Univ Warsaw, Fac Chem, Pasteura 1, PL-02093 Warsaw, Poland..
    Häggman, Leif
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry. Univ Paris 07, Sorbonne Paris Cite, CNRS, UMR 7086,ITODYS, 15 Rue Jean Antoinede Baif, F-75205 Paris 13, France.;Sungkyankwan Univ, Sch Chem Engn, Suwon 440746, South Korea..
    Physicochemical identity and charge storage properties of battery-type nickel oxide material and its composites with activated carbon2016In: Electrochimica Acta, ISSN 0013-4686, E-ISSN 1873-3859, Vol. 194, p. 480-488Article in journal (Refereed)
    Abstract [en]

    The structural properties of annealed nickel oxide and its composites with activated carbon (synthesized via simple precipitation methods) have been addressed using X-ray diffraction, X-ray photoelectron spectroscopy, nitrogen adsorption/desorption method and scanning electron microscopy. The charge storage properties of materials have also been investigated in three-and two-electrode configurations by means of cyclic voltammetry and galvanostatic charging/discharging in alkaline media. The results are consistent with the view that, depending on a method of preparation, the resulting nickel oxide films may exhibit redox characteristics different from that typically observed for nickel oxide-based materials. It is demonstrated that faradaic-type (redox) reactions, that are typical for battery-like materials, contribute predominantly to the high electrode capacity of 257C g(-1) (at 0.1 A g(-1)). By combining nickel oxide with a capacitive material such as activated carbon within the two-electrode symmetric cell, systems with increased charge-storage capabilities have been obtained. The fact, that the voltage window of nickel oxide-based cell has been broadened positively from 0.6 V to 1 V upon introduction of activated carbon, has also resulted in the increase of the cell's energy and power densities as well. 

  • 14.
    Bauer, Christophe
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Mukhtar, Emad
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Electron injection and recombination in Ru(dcbpy)(2)(NCS)(2) sensitized nanostructured ZnO2001In: JOURNAL OF PHYSICAL CHEMISTRY B, ISSN 1089-5647, Vol. 105, no 24, p. 5585-5588Article in journal (Refereed)
    Abstract [en]

    The dynamics of electron-transfer processes between bis(tetrabutylammonium) cis-bis(thiocyanato)bis(2,2'-bypiridine-4,4'-dicarboxylato)ruthenium(II) (called N719) and nanostructured ZnO films have been investigated by femtosecond and nanosecond spectrosco

  • 15.
    Bauer, Christophe
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Mukhtar, Emad
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Interfacial Elevtron-Transfer Dynamics in Ru(tcterpy)(NCS)3-Sensiitized TiO2 Nanocrystalline Solar Cells2002In: Journal of Physical Chemistry B, ISSN 1520-6106, E-ISSN 1520-5207, Vol. 106, p. 12693-12704Article in journal (Refereed)
    Abstract [en]

    The anchoring of the ruthenium dye {(C4H9)4N}[Ru(Htcterpy)(NCS)3] (with tcterpy = 4,4‘,4‘‘-tricarboxy-2,2‘:6‘,2‘‘-terpyridine), the so-called black dye, onto nanocrystalline TiO2 films has been characterized by UV−vis and FT-IR spectroscopies. FT-IR spectroscopy data suggest that dye molecules are bound to the surface by a bidentate binuclear coordination mode. The interfacial electron-transfer (ET) dynamics has been investigated by femtosecond pump−probe transient absorption spectroscopy and nanosecond laser flash photolysis. The electron-injection process from the dye excited state into the TiO2 conduction band is biexponential with a fast component (200 ± 50 fs) and a slow component (20 ps). These two components can be attributed to the electron injection from the initially formed and the relaxed dye excited states, respectively. Nanosecond kinetic data suggest the existence of two distinguishable regimes (I and II) for the rates of reactions between injected electrons and oxidized dye molecules or oxidized redox species (D+ or I2•-). The frontier between these two regimes is defined by the number of injected electrons per particle (Ne), which was determined to be about 1. The present kinetic study was undertaken within regime I (Ne > 1). Under these conditions, the back-electron-transfer kinetics is comparable to that in systems with other ruthenium complexes adsorbed onto TiO2. The reduction of oxidized dye molecules by iodide results in the formation of I2•- on a very fast time scale (<20 ns). Within regime I, the decay of I2•- occurs in 100 ns via reaction with injected electrons (I2•- + e- → 2I-). In regime II (Ne ≤ 1), which corresponds to the normal operating conditions of dye-sensitized solar cells, the decay of I2•- is very slow and likely occurs via the dismutation reaction (2I2•-→ I- + I3-). Our results predict that, under high light intensity (Ne > 1), the quantum efficiency losses in dye-sensitized solar cells will be important because of the dramatic acceleration of the reaction between I2•- and injected electrons. Mechanisms for the ET reactions involving injected electrons are proposed. The relevance of the present kinetic studies for dye-sensitized nanocrystalline solar cells is discussed.

  • 16.
    Bauer, Christophe
    et al.
    Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Physical Chemistry. Department of Physical and Analytical Chemistry, Physical Chemistry I.
    Boschloo, Gerrit
    Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Physical Chemistry. Department of Physical and Analytical Chemistry, Physical Chemistry I.
    Mukhtar, Emad
    Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Physical Chemistry. Department of Physical and Analytical Chemistry, Physical Chemistry I.
    Hagfeldt, Anders
    Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Physical Chemistry. Department of Physical and Analytical Chemistry, Physical Chemistry I.
    Ultrafast relaxation dynamics of charge carriers relaxation in ZnO nanocrystalline thin films2004In: Chemical Physics Letters, Vol. 387, no 1-3, p. 176-181Article in journal (Refereed)
  • 17.
    Bauer, Christophe
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Mukhtar, Emad
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Ultrafast studies of electron injection in Ru dye sensitized SnO2 nanocrystalline thin film2002In: International Journal of Photoenergy, Vol. 4, p. 17-20Article in journal (Refereed)
  • 18.
    Beermann, Niclas
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Trapping of electrons in nanostructured TiO2 studied by photocurrent transients2002In: Journal of Photochemistry and Photobiology A: Chemistry, Vol. 152, p. 213-218Article in journal (Refereed)
  • 19.
    Beermann, Niclas
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Vayssieres, L
    Lindquist, Sten-Eric
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Photoelectrochemical studies of oriented nanorod thin films of hematite2000In: JOURNAL OF THE ELECTROCHEMICAL SOCIETY, ISSN 0013-4651, Vol. 147, no 7, p. 2456-2461Article in journal (Refereed)
    Abstract [en]

    Thin films consisting of nanorods of hematite (alpha-Fe2O3) with controlled orientation onto transparent conductive glass substrates have been tested as photoelectrochemical cells. These films allow a more efficient transport and collection of photogenera

  • 20.
    Benkö, Gabor
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Skårman, Björn
    Wallenberg, Reine
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Sundström, Villy
    Yartsev, Arkady P.
    Particle Size and Crystallinity Dependent Electron Injection in Flourescein 27-Sensitized TiO2 Films2003In: Journal of Physical Chemistry B, Vol. 107, p. 1370-1375Article in journal (Refereed)
  • 21.
    Bi, Dongqin
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    High-Efficient Solid-State Perovskite Solar Cell Without Lithium Salt in the Hole Transport Material2014In: NANO, ISSN 1793-2920, Vol. 9, no 5, p. 1440001-Article in journal (Refereed)
    Abstract [en]

    CH3NH3PbX (X Br, I, Cl) perovskites have recently been used as light absorbers in hybrid organic-inorganic solid-state solar cells, with efficiencies above 15%. To date, it is essential to add Lithium bis(Trifluoromethanesulfonyl) Imide (LiTFSI) to the hole transport materials (HTM) to get a higher conductivity. However, the detrimental er effect of high LiTFSI concentration on the charge transport, DOS in the conduction band of the TiO2 substrate and device stability results in an overall compromise for a satisfactory device. Using a higher mobility hole conductor to avoid lithium salt is an interesting alternative. Herein, we successfully made an efficient perovskite solar cell by applying a hole conductor PTAA (Poly[ bis(4-phenyl) (2,4,6-trimethylphenyl)amine]) in the absence of LiTFSI. Under AM 1.5 illumination of 100mW/cm(2), an efficiency of 10.9% was achieved, which is comparable to the efficiency of 12.3% with the addition of 1.3mM LiTFSI. An unsealed device without Li+ shows interestingly a promising stability.

  • 22.
    Bi, Dongqin
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Schwarzmueller, Stefan
    Yang, Lei
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Johansson, Erik M. J.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Efficient and stable CH3NH3PbI3-sensitized ZnO nanorod array solid-state solar cells2013In: Nanoscale, ISSN 2040-3364, E-ISSN 2040-3372, Vol. 5, no 23, p. 11686-11691Article in journal (Refereed)
    Abstract [en]

    We report for the first time the use of a perovskite (CH3NH3PbI3) absorber in combination with ZnO nanorod arrays (NRAs) for solar cell applications. The perovskite material has a higher absorption coefficient than molecular dye sensitizers, gives better solar cell stability, and is therefore more suited as a sensitizer for ZnO NRAs. A solar cell efficiency of 5.0% was achieved under 1000 W m(-2) AM 1.5 G illumination for a solar cell with the structure: ZnO NRA/CH3NH3PbI3/spiro-MeOTAD/Ag. Moreover, the solar cell shows a good long-term stability. Using transient photocurrent and photovoltage measurements it was found that the electron transport time and lifetime vary with the ZnO nanorod length, a trend which is similar to that in dye-sensitized solar cells, DSCs, suggesting a similar charge transfer process in ZnO NRA/CH3NH3PbI3 solar cells as in conventional DSCs. Compared to CH3NH3PbI3/TiO2 solar cells, ZnO shows a lower performance due to more recombination losses.

  • 23.
    Bi, Dongqin
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström.
    El-Zohry, Ahmed M.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Improved Morphology Control Using a Modified Two-Step Method for Efficient Perovskite Solar Cells2014In: ACS Applied Materials and Interfaces, ISSN 1944-8244, E-ISSN 1944-8252, Vol. 6, no 21, p. 18751-18757Article in journal (Refereed)
    Abstract [en]

    A two-step wet chemical synthesis method for methylammonium lead(II) triiodide (CH3NH3PbI3) perovskite is further developed for the preparation of highly reproducible solar cells, with the following structure: fluorine-doped tin oxide (FTO)/TiO2 (compact)/TiO2 (mesoporous)/CH3NH3PbI3/spiro-OMeTAD/Ag. The morphology of the perovskite layer could be controlled by careful variation of the processing conditions. Specifically, by modifying the drying process and inclusion of a dichloromethane treatment, more uniform films could be prepared, with longer emission lifetime in the perovskite material and longer electron lifetime in solar cell devices, as well as faster electron transport and enhanced charge collection at the selective contacts. Solar cell efficiencies up to 13.5% were obtained.

  • 24.
    Bi, Dongqin
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    El-Zohry, Ahmed M.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Unraveling the Effect of PbI2 Concentration on Charge Recombination Kinetics in Perovskite Solar Cells2015In: ACS Photonics, E-ISSN 2330-4022, Vol. 2, no 5, p. 589-594Article in journal (Refereed)
    Abstract [en]

    CH3NH3PbI3 perovskite solar cells have rapidly risen to the forefront of emerging photovoltaic technologies. A solution-based, two-step method was reported to enhance the reproducibility of these solar cells. In this method, first a coating of PbI2 is applied by spin-coating onto a TiO2-coated substrate, followed by a dip in a methylammonium iodide solution, leading to conversion to CH3NH3PbI3. The concentration of PbI2 in the spin-coating solution is a very important factor that affects the infiltration of the perovskite and the amount deposited. The best solar cell performance of 13.9% was obtained by devices prepared using 1.0 M of PbI2 in dimethylformamide. These devices also had the longest electron lifetime and shortest carrier transport time, yielding lowest recombination losses. Rapid quenching of the perovskite emission is found in device-like structures, suggesting reasonably good efficient carrier extraction at the TiO2 interface and quantitative extraction at the spiro-OMeTAD interface.

  • 25.
    Bi, Dongqin
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Moon, Soo-Jin
    Häggman, Leif
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Yang, Lei
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Johansson, Erik M. J.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Nazeeruddin, Mohammad K.
    Graetzel, Michael
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Using a two-step deposition technique to prepare perovskite (CH3NH3PbI3) for thin film solar cells based on ZrO2 and TiO2 mesostructures2013In: RSC Advances, ISSN 2046-2069, E-ISSN 2046-2069, Vol. 3, no 41, p. 18762-18766Article in journal (Refereed)
    Abstract [en]

    A two-step deposition technique is used for preparing CH3NH3PbI3 perovskite solar cells. Using ZrO2 and TiO2 as a mesoporous layer, we obtain an efficiency of 10.8% and 9.5%, respectively, under 1000 W m(-2) illumination. The ZrO2 based solar cell shows higher photovoltage and longer electron lifetime than the TiO2 based solar cell.

  • 26.
    Bi, Dongqin
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Yang, Lei
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Johansson, Erik M. J.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Effect of Different Hole Transport Materials on Recombination in CH3NH3PbI3 Perovskite-Sensitized Mesoscopic Solar Cells2013In: Journal of Physical Chemistry Letters, ISSN 1948-7185, E-ISSN 1948-7185, Vol. 4, no 9, p. 1532-1536Article in journal (Refereed)
    Abstract [en]

    We report on perovskite (CH3NH3)PbI3-sensitized solid-state solar cells using spiro-OMeTAD, poly(3-hexylthiophene-2,5-diyl) (P3HT) and 4-(diethylamino)benzaldehyde diphenylhydrazone (DEH) as hole transport materials (HTMs) with a light to electricity power conversion efficiency of 8.5%, 4.5%, and 1.6%, respectively, under AM 1.5G illumination of 1000 W/m(2) intensity. Photoinduced absorption spectroscopy (PIA) shows that hole transfer occurs from the (CH3NH3)PbI3 to HTMs after excitation of (CH3NH3)PbI3. The electron lifetime (tau(e)) in these devices are in the order Spiro-OMeTAD > P3HT > DEH, while the charge transport time (t(tr)) is rather similar. The difference in tau(e) can therefore explain the lower efficiency of the devices based on P3HT and DEH. This report shows that the nature of the HTM is essential for charge recombination and elucidates that finding an optimal HTM for the perovskite solar cell includes controlling the perovskite/HTM interaction. Design routes for new HTMs are suggested.

  • 27.
    Borgström, Magnus
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry I.
    Blart, Errol
    Boschloo, Gerrit
    Mukhtar, Emad
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry I.
    Hagfeldt, Anders
    Hammarström, Leif
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry I.
    Odobel, Fabrice
    Sensitized Hole Injection of Phosphorus Porphyrin into NiO: Toward New Photovoltaic Devices2005In: Journal of Physical Chemistry B, ISSN 1520-6106, E-ISSN 1520-5207, Vol. 109, no 48, p. 22928-22934Article in journal (Refereed)
    Abstract [en]

    This paper describes the preparation and the characterization of a photovoltaic cell based on the sensitization of a wide band gap p-type semiconductor (NiO) with a phosphorus porphyrin. A photophysical study with femtosecond transient absorption spectroscopy showed that light excitation of the phosphorus porphyrin chemisorbed on NiO particles induces a very rapid interfacial hole injection into the valence band of NiO, occurring mainly on the 2-20 ps time scale. This is followed by a recombination in which ca. 80% of the ground-state reactants are regenerated within 1 ns. A photoelectrochemical device, prepared with a nanocrystalline NiO electrode coated with the phosphorus porphyrin, yields a cathodic photocurrent indicating that electrons indeed flow from the NiO electrode toward the solution. The low incident-to-photocurrent efficiency (IPCE) can be rationalized by the rapid back recombination reaction between the reduced sensitizer and the injected hole which prevents an efficient regeneration of the sensitizer ground state from the iodide/triiodide redox mediator. To the best of our knowledge, this work represents the first example of a photovoltaic cell in which a mechanism of hole photoinjection has been characterized.

  • 28.
    Boschloo, Gerrit
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Gibson, Elizabeth A.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Photomodulated Voltammetry of Iodide/Triiodide Redox Electrolytes and Its Relevance to Dye-Sensitized Solar Cells2011In: Journal of Physical Chemistry Letters, ISSN 1948-7185, E-ISSN 1948-7185, Vol. 2, no 24, p. 3016-3020Article in journal (Refereed)
    Abstract [en]

    Photomodulated voltammetry was used to determine the redox potentials of the diiodide radical (I(2)(-center dot)) in water, acetonitrile, and 3-methoxypropionitrile. Iodide/triiodide redox electrolytes were exposed to modulated blue light, resulting in I(2)(-center dot) generation. Using transparent fluorine-doped tinoxide (FTO) electrodes, two modulated photocurrent waves could be discerned in the voltammogram, from which the formal potentials for oxidation and reduction reactions of the diiodide radical were determined. E(0)'(I(2)(-center dot)/I(-)) was found to be +0.79 and +1.04 V versus NHE in acetonitrile and water, respectively. These values give guidelines for E(0)'(D(+)/D) required for efficient regeneration of dyes used in dye-sensitized solar cells.

  • 29.
    Boschloo, Gerrit
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry I.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry I.
    Activation Energy of Electron Transport in Dye-Sensitized TiO2 Solar Cells2005In: Journal of Physical Chemistry B, ISSN 1520-6106, E-ISSN 1520-5207, Vol. 109, no 24, p. 12093-12098Article in journal (Refereed)
    Abstract [en]

    Various characteristics of dye-sensitized nanostructured TiO2 solar cells, such as electron transport and electron lifetime, were studied in detail using monochromatic illumination conditions. The electron transport was found to be a thermally activated process with activation energies in the range of 0.10-0.15 eV for light intensities that varied 2 orders of magnitude. Electron lifetimes were determined using a new method and found to be significantly larger (>1 s) than previously determined. An average potential was determined for electrons in the nanostructured TiO2 under illumination in short-circuit conditions. This potential is about 0.2 V lower than the open-circuit potential at the same light intensity. The electron transport time varies exponentially with the internal potential at short-circuit conditions, indicating that the gradient in the electrochemical potential is the driving force for electron transport in the nanostructured TiO2 film. The applicability of the conventionally used trapping/detrapping model is critically analyzed. Although experimental results can be fitted using a trapping/detrapping model with an exponential distribution of traps, the distribution parameters differ significantly between different types of experiment. Furthermore, the experimental activation energies for electron transport are smaller than those expected in a trapping/detrapping model.

  • 30.
    Boschloo, Gerrit
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Characteristics of the Iodide/Triiodide Redox Mediator in Dye-Sensitized Solar Cells2009In: Accounts of Chemical Research, ISSN 0001-4842, E-ISSN 1520-4898, Vol. 42, no 11, p. 1819-1826Article, review/survey (Refereed)
    Abstract [en]

    Dye-sensitized solar cells (DSCs) have gained widespread interest because of their potential for low-cost solar energy conversion. Currently, the certified record efficiency of these solar cells is 11.1%, and measurements of their durability and stability suggest lifetimes exceeding 10 years under operational conditions, The DSC is a photoelectrochemical system: a monolayer of sensitizing dye is adsorbed onto a mesoporous TiO2 electrode, and the electrode is sandwiched together with a counter electrode. An electrolyte containing a redox couple fills the gap between the electrodes.

    The redox couple is a key component of the DSC. The reduced part of the couple regenerates the photo-oxidized dye. The formed oxidized species diffuses to the counter electrode, where it is reduced. The photovoltage of the device depends on the redox couple because it sets the electrochemical potential at the counter electrode. The redox couple also affects the electrochemical potential of the TiO2 electrode through the recombination kinetics between electrons in TiO2 and oxidized redox species.

    This Account focuses on the special properties of the iodide/triiodide (I-/I-3(-)) redox couple in dye-sensitized solar cells. It has been the preferred redox couple since the beginning of DSC development and still yields the most stable and efficient DSCs. Overall, the iodide/triiodide couple has good solubility, does not absorb too much light, has a suitable redox potential, and provides rapid dye regeneration. But what distinguishes I-/I-3(-) from most redox mediators is the very slow recombination kinetics between electrons in TiO2 and the oxidized part of the redox couple, triiodide. Certain dyes adsorbed at TiO2 catalyze this recombination reaction, presumably by binding iodine or triiodide.

    The standard potential of the iodide/triiodide redox couple is 0.35 V (versus the normal hydrogen electrode, NHE), and the oxidation potential of the standard DSC-sensitizer (Ru(dcbpy)(2)(NCS)(2)) is 1.1 V. The driving force for reduction of oxidized dye is therefore as large as 0.75 V. This process leads to the largest internal potential loss in DSC devices. We expect that overall efficiencies above 15% might be achieved if half of this internal potential loss could be gained.

    The regeneration of oxidized dye with iodide leads to the formation of the diiodide radical (I-2(-center dot)). The redox potential of the I-2(-center dot)/I- couple must therefore be considered when determining the actual driving force for dye regeneration. The formed I-2(-center dot) disproportionates to I-3(-) and I-, which leads to a large loss in potential energy.

  • 31.
    Boschloo, Gerrit
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Photoinduced absorption spectroscopy of dye-sensitized nanostructured TiO22003In: Chemical Physics Letters, Vol. 370, p. 381-386Article in journal (Refereed)
  • 32.
    Boschloo, Gerrit
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Spectroelectrochemistry of nanostructured NiO2001In: JOURNAL OF PHYSICAL CHEMISTRY B, ISSN 1089-5647, Vol. 105, no 15, p. 3039-3044Article in journal (Refereed)
    Abstract [en]

    Transparent nanostructured NiO electrodes have been prepared by heating Ni(OH)(2) sol-gel films at a temperature of 300-320 degreesC. Nanostructured NiO (bunsenite) behaves as a p-type semiconductor and has an indirect band gap of 3.55 eV. It shows a stro

  • 33.
    Boschloo, Gerrit
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Lindström, Henrik
    Magnusson, Eva
    Holmberg, Anna
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Optimization of dye-sensitized solar cells prepared by compression method2002In: Journal of Photochemistry and Photobiology A: Chemistry, Vol. 148, p. 11-15Article in journal (Refereed)
  • 34. Bruder, Ingmar
    et al.
    Karlsson, Martin
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Eickenmeyer, Felix
    Hwang, Jaehyung
    Erk, Peter
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Weis, Jürgen
    Pschirer, Neil
    Efficient organic tandem cell combining a solid state dye-sensitized and a vacuum deposited bulk heterojunction solar cell2009In: Solar Energy Materials and Solar Cells, ISSN 0927-0248, E-ISSN 1879-3398, Vol. 93, no 10, p. 1896-1899Article in journal (Refereed)
    Abstract [en]

    In this letter, we report on an efficient organic tandem solar cell combining a solid state dye-sensitized with a ZnPc/C60-based, vacuum deposited bulk heterojunction solar cell. Due to an effective serial connection of both subcells and to the complementary absorption of the dyes used, a power conversion efficiency of ηp=(6.0±0.1)% was achieved under simulated AM 1.5 illumination. The device parameters are , and FF=(54±1)%.

  • 35.
    Burnside, S
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Winkel, S
    Brooks, K
    Shklover, V
    Gratzel, M
    Hinsch, A
    Kinderman, R
    Bradbury, C
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Pettersson, H
    Deposition and characterization of screen-printed porous multi-layer thick film structures from semiconducting and conducting nanomaterials for use in photovoltaic devices2000In: JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, ISSN 0957-4522, Vol. 11, no 4, p. 355-362Article in journal (Refereed)
    Abstract [en]

    Three-layer structures of thick (> 5 mu m) films of nanosized titanium dioxide, zirconium dioxide, and carbon have been screen-printed on a semi-production level for use in photosensitized photovoltaic devices. The films have been characterized using scan

  • 36.
    Cappel, Ute B.
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Feldt, Sandra M.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Schoeneboom, Jan
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    The influence of local electric fields on photoinduced absorption in dye-sensitized solar cells.2010In: Journal of the American Chemical Society, ISSN 0002-7863, E-ISSN 1520-5126, Vol. 132, no 26, p. 9096-9101Article in journal (Refereed)
    Abstract [en]

    The dye-sensitized solar cell (DSC) challenges conventional photovoltaics with its potential for low-cost production and its flexibility in terms of color and design Transient absorption spectroscopy is widely used to unravel the working mechanism of DSCs A surprising, unexplained feature observed in these studies is an apparent bleach of the ground-state absorption of the dye, under conditions where the dye is in the ground state. Here, we demonstrate that this feature can be attributed to a change of the local electric field affecting the absorption spectrum of the dye, an effect related to the Stark effect first reported in 1913 We present a method for measuring the effect of an externally applied electric field on the absorption of dye monolayers adsorbed on flat TiO2 substrates. The measured signal has the shape of the first derivative of the absorption spectra of the dyes and reverses sign along with the reversion of the direction of the change in dipole moment upon excitation relative to the TiO2 surface A very similar signal is observed in photoinduced absorption spectra of dye-sensitized TiO2 electrodes under solar cell conditions, demonstrating that the electric field across the dye molecules changes upon illumination This result has important implications for the analysis of transient absorption spectra of DSCs and other molecular optoelectronic devices and challenges the interpretation of many previously published results.

  • 37.
    Cappel, Ute B.
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry.
    Gibson, Elizabeth A.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry.
    Dye regeneration by spiro-MeOTAD in solid state dye-sensitized solar cells studied by photoinduced absorption spectroscopy and spectroelectrochemistry.2009In: The Journal of Physical Chemistry C, ISSN 1932-7447, E-ISSN 1932-7455, Vol. 113, no 15, p. 6275-6281Article in journal (Refereed)
    Abstract [en]

    Photoinduced absorption (PIA) spectroscopy is presented as a tool for the systematic study of dye regeneration and pore filling in solid state dye-sensitized solar cells (DSC). Oxidn. potentials and extinction coeffs. for oxidized species of the perylene dye, ID28, on TiO2 and of the hole conductor, 2,2'7,7'-tetrakis-(N,N-di-p-methoxyphenyl-amine)-9,9'-spirobifluorene (spiro-MeOTAD), were detd. by spectroelectrochem. The onset of oxidn. of a solid film of spiro-MeOTAD was found to be 0.15 V vs. Fc/Fc+ and extinction coeffs. of spiro-MeOTAD+ were found to be 33 000 M-1 cm-1 at 507 nm and 8500 M-1 cm-1 at 690 nm. Electrons in TiO2 films were shown to alter the ground-state absorption spectra of ID28 attached to TiO2. PIA measurements indicated a good contact between ID28 and spiro-MeOTAD for different spiro-MeOTAD concns. for both 2- and 6-micro m thick TiO2 films. We discuss the possibility of estg. the quality of pore filling from the positions of absorption peaks. Results suggested that with a spiro-MeOTAD concn. of 300 mg mL-1 in chlorobenzene, a uniform distribution of spiro-MeOTAD in the pores of the 6-micro m thick TiO2 film could be achieved.

  • 38.
    Cappel, Ute B.
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry.
    Karlsson, Martin H.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry.
    Pschirer, G
    Eickemeyer, Felix
    Schoeneboom, Jan
    Erk, Peter
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry.
    A broadly absorbing perylene dye for solid-state dye-sensitized solar cells.2009In: The Journal of Physical Chemistry C, ISSN 1932-7447, E-ISSN 1932-7455, Vol. 113, no 33, p. 14595-14597Article in journal (Refereed)
    Abstract [en]

    We present a new perylene sensitizer, ID 176, for dye-sensitized solar cells (DSCs). The dye has the capability for very high photocurrents due to strong absorption from 400 to over 700 rim. Photocurrents Of LIP to 9 mA cm(-2) were achieved in solid-state DSCs employing the hole conductor 2,2'7,7'-tetrakis-(NN-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-MeOTAD), with a conversion efficiency of 3.2%. In contrast, the sensitizer did not perform well in conjunction with liquid iodide/tri-iodide electrolytes, suggesting a difference in the injection and regeneration mechanisms in these two types of dye-sensitized solar cells.

  • 39.
    Cappel, Ute B.
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Smeigh, Amanda L.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science, Chemical Physics.
    Plogmaker, Stefan
    Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy, Surface and Interface Science.
    Johansson, Erik M. J.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Rensmo, Håkan
    Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy, Surface and Interface Science.
    Hammarström, Leif
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Photochemistry and Molecular Science, Chemical Physics.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Characterization of the Interface Properties and Processes in Solid State Dye-Sensitized Solar Cells Employing a Perylene Sensitizer2011In: The Journal of Physical Chemistry C, ISSN 1932-7447, E-ISSN 1932-7455, Vol. 115, no 10, p. 4345-4358Article in journal (Refereed)
    Abstract [en]

    We recently reported on a perylene sensitizer, ID176, which performs much better in solid state dye-sensitized solar cells than in those using liquid electrolytes with iodide/tri-iodide as the redox couple (J. Phys. Chem. C2009, 113, 14595-14597). Here, we present a characterization of the sensitizer and of the TiO2/dye interface by UV-visible absorption and fluorescence spectroscopy, spectroelectrochemistry, photoelectron spectroscopy, electroabsorption spectroscopy, photoinduced absorption spectroscopy, and femtosecond transient absorption measurements. We report that the absorption spectrum of the sensitizer is red-shifted by addition of lithium ions to the surface due to a downward shift of the excited state level of the sensitizer, which is of the same order of magnitude as the downward shift of the titanium dioxide conduction band edge. Results from photoelectron spectroscopy and electrochemistry suggest that the excited state is largely located below the conduction band edge of TiO2 but that there are states in the band gap of TiO2 which might be available for photoinduced electron injection. The sensitizer was able to efficiently inject into TiO2, when a lithium salt was present on the surface, while injection was much less effective in the absence of lithium ions or in the presence of solvent. In the presence of the hole conductor 2,2-,7,7-tetrakis-(N,N-di-p-methoxyphenyl-amine)-9,9-spirobifluorene (spiro-MeOTAD) and LiTFSI, charge separation was monitored by the emergence of a Stark shift of the dye in transient absorption spectra, and both injection and regeneration appear to be completed within 1 ps. Regeneration by spiro-MeOTAD is therefore several orders of magnitude faster than regeneration by iodide, and ID176 can even be photoreduced by spiro-MeOTAD.

  • 40.
    Cappel, Ute
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Plogmaker, Stefan
    Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy.
    Johansson, Erik M. J.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Rensmo, Håkan
    Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy.
    Energy Alignment and Surface Dipoles of Rylene Dyes adsorbed to TiO2 nanoparticles2011In: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 13, no 32, p. 14767-14774Article in journal (Refereed)
    Abstract [en]

    The energy loss in dye-sensitized solar cells calculated from the energy difference between the lowest electronic transition of the dye and the obtained open-circuit voltage is often 1 eV or even more. To minimize this loss, it is important to accurately determine the energy alignment at the TiO2/dye/redox-mediator interface. In this study, we compared the results from electrochemistry and photoelectron spectroscopy for determining the energy alignment of three rylene dyes, two of which absorb relatively far in the red. The trends observed with the methods were different, as in the former, the energy alignment is measured relative to an external reference and includes contributions from solvent reorganization energies, while in the latter, it is measured relative to the energetics of the TiO2 and is lacking such contributions. The influence of the dyes' dipole moments on the energetics of the TiO2 was also measured and explained some of the differences in trends. Finally, we compared the injection efficiencies of the two red-absorbing dyes and found that the differences in injection efficiencies can be better explained using the energy alignment determined from photoelectron spectroscopy. This shows that the method for measuring the energetics of a DSC should be chosen according to what process one intends to study.

  • 41.
    D'Amario, Luca
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Hammarström, Leif
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Tuning of Conductivity and Density of States of NiO Mesoporous Films Used in p-Type DSSCs2014In: The Journal of Physical Chemistry C, ISSN 1932-7447, E-ISSN 1932-7455, Vol. 118, no 34, p. 19556-19564Article in journal (Refereed)
    Abstract [en]

    Nickel oxide has been used as the mesoporous electrode material for p-type dye sensitized solar cell (DSSC) for many years, but no high efficiency cells have been obtained yet. The poor results are commonly attributed to the lack of conductivity of the NiO film. In this paper we studied the electrical conduction of NiO mesoporous film with cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). We used unsensitized NiO on FTO as an electrode with no dye adsorbed on the surface. Tests made with a DSSC device-like cell (FTO-Pt-I-/I-3(-)-NiO-FTO) showed a surprisingly high Faradaic current (20 mA/cm(-2) at 1 V), proving a good electrical conductivity of mesoporous NiO. We also used lithium as dopant to improve the electrical properties of the film. The Li-doping resulted in widening the inert (not conductive) window in the CV plot. The EIS analysis clarified that this behavior is due to a strong dependence of the valence band shape and position with respect to the Li-doping concentration. Our results show that DSSC performance does not need to be limited by the conductivity of mesoporous NiO, which encourages more effort in p-type DSSC research based on this material.

  • 42.
    de Vries, J.G
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Scholtens, B.J.R.
    Maes, I.
    Grätzel, S.
    Winkel, S.
    Burnside, S.
    Wolf, A.Hinsch
    Kroon, J.M.
    Ahlse, M.
    Tjerneld, F.
    Ferrero, G.
    Bruno, E.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Bradbury, C.
    Carlsson, P.
    Pettersson, H.
    Verspeek-Rip, C.-M.
    Enniga, I.C.
    Negative Ames-test of cis-di(thiocyanato)-N, N´-bis(4,4´-dicarboxy-2,2´-bipyridine)Ru(II), the sentisizer dye of the nanocrystalline TiO2 solar cell2000In: Solar Energy Materials & Solar Cells, no 60, p. 43-49Article in journal (Refereed)
  • 43.
    Dunn, Halina K.
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Westin, Per-Oskar
    Staff, Daniel R.
    Peter, Laurence M.
    Waker, Alison B.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Determination of the Electron Diffusion Length in Dye-Sensitized Solar Cells by Substrate Contact Patterning2011In: The Journal of Physical Chemistry C, ISSN 1932-7447, E-ISSN 1932-7455, Vol. 115, no 28, p. 13932-13937Article in journal (Refereed)
    Abstract [en]

    A new method to estimate the electron diffusion length in dye-sensitized solar cells (DSCs) is presented. DSCs were fabricated on conducting glass substrates that were patterned by laser ablation of the fluorine-doped tin oxide coating to form parallel contact strips separated by uncontacted strips of the same width. The relative collection efficiency was measured as a function of the gap between the contact strips, which determines the lateral distance traveled by electrons to reach the contacts. To avoid complications arising from non-linear recombination kinetics, current measurements were performed using small amplitude perturbations of the electron density close to open circuit and the maximum power point to minimize electron density gradients in the film. One and two-dimensional solutions of the continuity equation for electron transport and back reaction predict that the relative collection efficiency should fall as spacing between the contact strips exceeds the electron diffusion length and electrons are lost by back electron transfer during transit to the contacts. Measurements of the relative collection efficiency were fitted to the predicted dependence of the collection efficiency on the spacing between the contact strips to obtain the value of the electron diffusion length. The diffusion length is found to increase with voltage both at open circuit and at the maximum power point.

  • 44.
    Edvinsson, Tomas
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Materials Chemistry, Inorganic Chemistry.
    Pschirer, Niel
    Schöneboom, Jan
    Eickemeyer, Felix
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry.
    Photoinduced electron transfer from a terrylene dye to TiO2: Quantification of band edge shift effects2009In: Chemical Physics, ISSN 0301-0104, E-ISSN 1873-4421, Vol. 357, no 1-3, p. 124-131Article in journal (Refereed)
    Abstract [en]

    A terrylene chromophore exhibiting a high extinction coefficient has been developed as a sensitizer for photovoltaic applications. The photophysical and photochemical properties of the dye were analyzed both experimentally and theoretically. Terrylene-sensitized nanocrystalline TiO2 solar cells yielded good photocurrents providing more than 60% in external quantum efficiency. The photoinduced electron transfer from the dye to TiO2 was found to be very sensitive to conduction band edge shifts in TiO2 induced, either by changes in the composition of the redox electrolyte or by UV-illumination. This sensitivity was observed in quantum efficiencies for photocurrent generation of terrylene-sensitized solar cells and in photoinduced absorption experiments. The conduction band shifts were quantified using charge extraction methods. The observed sensitivity of the injection efficiency suggests that photoinduced electron transfer occurs from the relaxed excited state, possibly due to poor electronic coupling between TMIMA excited states and TiO2 conduction band states.

  • 45.
    Edwards, M O M
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry. Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry I. Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Electronics.
    Andersson, M
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry I. Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Electronics.
    Gruszecki, T
    Pettersson, H
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry I. Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Electronics.
    Thunman, Robert
    Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Solid State Electronics.
    Thuraisingham, G
    Vestling, Lars
    Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Solid State Electronics.
    Hagfeldt, A
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry. Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical and Analytical Chemistry, Physical Chemistry I. Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Electronics.
    Charge-discharge kinetics of electric-paint displays2004In: Journal of Electroanalytical Chemistry, ISSN 0022-0728, E-ISSN 1873-2569, Vol. 565, no 2, p. 175-184Article in journal (Refereed)
  • 46.
    Edwards, MOM
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Gruszecki, T
    Pettersson, H
    Sohlberg, R
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    'Electric-paint displays' with carbon counter electrodes2001In: ELECTROCHIMICA ACTA, ISSN 0013-4686, Vol. 46, no 13-14, p. 2187-2193Article in journal (Refereed)
    Abstract [en]

    'Electric-paint displays' are electrochromic displays with dyed nanostructured metal-oxide electrodes, e.g. viologen-derivatized nanostructured titanium dioxide electrodes. Such displays are particularly promising for applications with low switch frequenc

  • 47.
    Edwards, M.O.M.
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    Gruszecki, T.
    Pettersson, H.
    Thuraisingham, G.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Physical Chemistry.
    A semi-empirical model for the charging and discharging of electric-paint displays2002In: Electrochemical Communications, Vol. 4, p. 963-967Article in journal (Refereed)
  • 48.
    Ellis, Hanna
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Jiang, Roger
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Ye, Sofie
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry. Ecole Polytech Fed Lausanne, Lab Photomol Sci, Inst Chem Sci & Engn, EPFL FSB ISIC LSPM,Stn 6, CH-1015 Lausanne, Switzerland.; King Abdulaziz Univ, Ctr Excellence Adv Mat Res, Jeddah 215889, Saudi Arabia.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Development of high efficiency 100% aqueous cobalt electrolyte dye-sensitised solar cells2016In: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 18, no 12, p. 8419-8427Article in journal (Refereed)
    Abstract [en]

    In this study we report the application of three cobalt redox shuttles in 100% aqueous electrolyte dye-sensitised solar cells (DSCs). By using chloride as a counter-ion for cobalt bipyridine, cobalt phenanthroline and cobalt bipyridine pyrazole, the redox shuttles were made water soluble; no surfactant or further treatment was necessary. A simple system of merely the redox shuttles and 1-methylbenzimidazole (MBI) in water as an electrolyte in combination with an organic dye and a mesoporous PEDOT counter electrode was optimised. The optimisation resulted in an average efficiency of 5.5% (record efficiency of 5.7%) at 1 sun. The results of this study present promising routes for further improvements of aqueous cobalt electrolyte DSCs.

  • 49.
    Ellis, Hanna
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Kaufmann Eriksson, Susanna
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Feldt, Sandra
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Gabrielsson, Erik
    KTH, Organisk kemi.
    Lohse, Peter
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström.
    Lindblad, Rebecka
    Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy, Molecular and condensed matter physics.
    Sun, Licheng
    KTH, Organisk kemi.
    Rensmo, Håkan
    Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy, Molecular and condensed matter physics.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Linker Unit Modification of Triphenylamine-based Organic Dyes for Efficient Cobalt Mediated Dye-Sensitized Solar Cells2013In: The Journal of Physical Chemistry C, ISSN 1932-7447, E-ISSN 1932-7455, Vol. 117, no 41, p. 21029-21036Article in journal (Refereed)
    Abstract [en]

    Linker unit modification of donor-linker-acceptor-based organic dyes was investigated with respect to the spectral and physicochemical properties of the dyes. The spectral response for a series of triphenylamine (TPA)-based organic dyes, called LEG1-4, was shifted into the red wavelength region, and the extinction coefficient of the dyes was increased by introducing different substituted dithiophene units on the pi-conjugated linker. The photovoltaic performance of dye-sensitized solar cells (DSCs) incorporating the different dyes in combination with cobalt-based electrolytes was found to be dependent on dye binding. The binding morphology of the dyes on the TiO2 was studied using photoelectron spectroscopy, which demonstrated that the introduction of alkyl chains and different substituents on the dithiophene linker unit resulted in a larger tilt angle of the dyes with respect to the normal of the TiO2-surface, and thereby a lower surface coverage. The good photovoltaic performance for cobalt electrolyte-based DSCs found here and by other groups using TPA-based organic dyes with a cyclopentadithiophene linker unit substituted with alkyl chains was mainly attributed to the extended spectral response of the dye, whereas the larger tilt angle of the dye with respect to the TiO2-surface resulted in less efficient packing of the dye molecules and enhanced recombination between electrons in TiO2 and Co(III) species in the electrolyte.

  • 50.
    Ellis, Hanna
    et al.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Leandri, Valentina
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Boschloo, Gerrit
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Bergquist, Jonas
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - BMC, Analytical Chemistry.
    Shevchenko, Denys  
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - BMC, Analytical Chemistry.
    Laser desorption/ionization mass spectrometry of dye-sensitized solar cells: identification of the dye-electrolyte interaction2015In: Journal of Mass Spectrometry, ISSN 1076-5174, E-ISSN 1096-9888, Vol. 50, no 5, p. 734-739Article in journal (Refereed)
    Abstract [en]

    Dye-sensitized solar cells (DSCs) have great potential to provide sustainable electricity from sunlight. The photoanode in DSCs consists of a dye-sensitized metal oxide film deposited on a conductive substrate. This configuration makes the photoanode a perfect sample for laser desorption/ionization mass spectrometry (LDI-MS). We applied LDI-MS for the study of molecular interactions between a dye and electrolyte on the surface of a TiO2 photoanode. We found that a dye containing polyoxyethylene groups forms complexes with alkali metal cations from the electrolyte, while a dye substituted with alkoxy groups does not. Guanidinium ion forms adducts with neither of the two dyes.

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