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  • 1.
    Dawange, Monali
    et al.
    Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för kemi - BMC.
    Galkin, Maxim V.
    Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för kemi - BMC.
    Samec, Joseph S. M.
    Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för kemi - BMC.
    Selective Aerobic Benzylic Alcohol Oxidation of Lignin Model Compounds: Route to Aryl Ketones2015Ingår i: ChemCatChem, ISSN 1867-3880, E-ISSN 1867-3899, Vol. 7, nr 3, s. 401-404Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    A mild and chemoselective oxidation of the -alcohol in -O-4-ethanoaryl and -O-4-glycerolaryl ethers has been developed. The benzylic alcohols were selectively dehydrogenated to the corresponding ketones in 60-93% yield. A one-pot selective route to aryl ethyl ketones was performed. The catalytic system comprises recyclable heterogeneous palladium, mild reaction conditions, green solvents, and oxygen in air as oxidant. Catalytic amounts of a coordinating polyol were found pivotal for an efficient aerobic oxidation.

  • 2.
    Galkin, Maxim
    Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för kemi - BMC, Syntetisk organisk kemi.
    Palladium-catalyzed lignin valorization: Towards a lignin-based biorefinery2015Doktorsavhandling, sammanläggning (Övrigt vetenskapligt)
    Abstract [en]

    The work described in this thesis focuses on the cleavage of the β-O-4′ bond, which is the most abundant interunit linkage in the lignin polymer.

    In the first part, three methods based on palladium catalysis have been developed and their applicability has been verified using lignin model compounds. A transfer hydrogenolysis of the β-O-4′ bond using formic acid as a mild hydrogen donor together with a base. An aerobic oxidation of the benzylic alcohol motif in the β-O-4′ linkage to generate a key intermediate in the cleavage reaction was performed. A redox neutral cleavage of the β-O-4′ bond was accomplished in which no stoichiometric reducing or oxidizing agents were added.

    In the second part of the thesis, a mechanistic study is presented. The corresponding ketone from a dehydrogenation reaction of the benzylic alcohol motif was identified to be the key intermediate. This ketone and its enol tautomer was found to be responsible for the β-O-4′ bond cleavage reaction under the employed reaction conditions.

    In the final part of this thesis, the methodologies have been applied to native lignin. The depolymerization reaction was combined with organosolv pulping. This approach was successful, and together with cellulose and hemicellulose, propenyl aryls were generated in excellent yields directly from wood. In this transformation, the lignin derived molecules have been reduced by an endogenous hydrogen donor from the wood.

    Delarbeten
    1. Mild Heterogeneous Palladium-Catalyzed Cleavage of beta-O-4 '-Ether Linkages of Lignin Model Compounds and Native Lignin in Air
    Öppna denna publikation i ny flik eller fönster >>Mild Heterogeneous Palladium-Catalyzed Cleavage of beta-O-4 '-Ether Linkages of Lignin Model Compounds and Native Lignin in Air
    Visa övriga...
    2014 (Engelska)Ingår i: ChemCatChem, ISSN 1867-3880, E-ISSN 1867-3899, Vol. 6, nr 1, s. 179-184Artikel i tidskrift (Refereegranskat) Published
    Abstract [en]

    A mild and robust heterogeneous palladium-catalyzed CO bond cleavage of 2-aryloxy-1-arylethanols using formic acid as reducing agent in air was developed. The cleaved products were isolated in 92-98% yield; and by slightly varying the reaction conditions, a ketone, an alcohol, or an alkane can be generated in near-quantitative yield. This reaction is applicable to cleaving the -O-4-ether bond found in lignin polymers of different origin. The reaction was performed on a lignin polymer model to generate either the monomeric aryl ketone or alkane in a quantitative yield. Moderate depolymerization was achieved with native lignin at similar reaction conditions. Mechanistic studies under kinetic control indicate that an initial palladium-catalyzed dehydrogenation of the alcohol is followed by insertion of palladium to an enol equivalent. A palladium-formato complex reductively cleaves the palladium-enolate complex to generate the ketone.

    Nyckelord
    heterogeneous catalysis, cleavage reactions, green chemistry, palladium, polymers, lignin
    Nationell ämneskategori
    Naturvetenskap
    Identifikatorer
    urn:nbn:se:uu:diva-220309 (URN)10.1002/cctc.201300540 (DOI)000330636800023 ()
    Anmärkning

    De två första författarna delar första författarskapet.

    Tillgänglig från: 2014-03-17 Skapad: 2014-03-12 Senast uppdaterad: 2017-12-05Bibliografiskt granskad
    2. Selective Aerobic Benzylic Alcohol Oxidation of Lignin Model Compounds: Route to Aryl Ketones
    Öppna denna publikation i ny flik eller fönster >>Selective Aerobic Benzylic Alcohol Oxidation of Lignin Model Compounds: Route to Aryl Ketones
    2015 (Engelska)Ingår i: ChemCatChem, ISSN 1867-3880, E-ISSN 1867-3899, Vol. 7, nr 3, s. 401-404Artikel i tidskrift (Refereegranskat) Published
    Abstract [en]

    A mild and chemoselective oxidation of the -alcohol in -O-4-ethanoaryl and -O-4-glycerolaryl ethers has been developed. The benzylic alcohols were selectively dehydrogenated to the corresponding ketones in 60-93% yield. A one-pot selective route to aryl ethyl ketones was performed. The catalytic system comprises recyclable heterogeneous palladium, mild reaction conditions, green solvents, and oxygen in air as oxidant. Catalytic amounts of a coordinating polyol were found pivotal for an efficient aerobic oxidation.

    Nyckelord
    biomass valorization, heterogeneous catalysis, lignin, oxidation, palladium
    Nationell ämneskategori
    Kemi
    Identifikatorer
    urn:nbn:se:uu:diva-246820 (URN)10.1002/cctc.201402825 (DOI)000349147100005 ()
    Tillgänglig från: 2015-03-11 Skapad: 2015-03-10 Senast uppdaterad: 2017-12-04Bibliografiskt granskad
    3. Mild and Robust Redox-Neutral Pd/C-Catalyzed Lignol -O-4 Bond Cleavage Through a Low-Energy-Barrier Pathway
    Öppna denna publikation i ny flik eller fönster >>Mild and Robust Redox-Neutral Pd/C-Catalyzed Lignol -O-4 Bond Cleavage Through a Low-Energy-Barrier Pathway
    2015 (Engelska)Ingår i: ChemSusChem, ISSN 1864-5631, E-ISSN 1864-564X, Vol. 8, nr 13, s. 2187-2192Artikel i tidskrift (Refereegranskat) Published
    Abstract [en]

    A Pd/C catalyzed redox neutral CO bond cleavage of 2-aryloxy-1-arylethanols has been developed. The reactions are carried out at 80 degrees C, in air, using a green solvent system to yield the aryl ketones in near quantitative yields. Addition of catalytic amounts of a hydrogen source to the reaction mixture activates the catalyst to proceed through a low energy barrier pathway. Initial studies support a transfer hydrogenolysis reaction mechanism that proceeds through an initial dehydrogenation followed by an enol adsorption to Pd/C and a reductive CO bond cleavage.

    Nyckelord
    heterogeneous catalysis, lignin, palladium, reaction mechanisms, transfer hydrogenolysis
    Nationell ämneskategori
    Kemi
    Identifikatorer
    urn:nbn:se:uu:diva-259649 (URN)10.1002/cssc.201500117 (DOI)000357619000004 ()25925736 (PubMedID)
    Forskningsfinansiär
    Energimyndigheten
    Tillgänglig från: 2015-08-20 Skapad: 2015-08-10 Senast uppdaterad: 2017-12-04Bibliografiskt granskad
    4. Selective Route to 2-Propenyl Aryls Directly from Wood by a Tandem Organosolv and Palladium-Catalysed Transfer Hydrogenolysis
    Öppna denna publikation i ny flik eller fönster >>Selective Route to 2-Propenyl Aryls Directly from Wood by a Tandem Organosolv and Palladium-Catalysed Transfer Hydrogenolysis
    2014 (Engelska)Ingår i: ChemSusChem, ISSN 1864-5631, E-ISSN 1864-564X, Vol. 7, nr 8, s. 2154-2158Artikel i tidskrift (Refereegranskat) Published
    Abstract [en]

    A tandem organosolv pulping and Pd-catalysed transfer hydrogenolysis depolymerisation and deoxygenation has been developed. The tandem process generated 2-methoxy-4-(prop-1-enyl)phenol in 23 % yield (92 % theoretical monomer yield) starting from pine wood and 2,6-dimethoxy-4-(prop-1-enyl)phenol in 49 % yield (92 % theoretical monomer yield) starting from birch wood. Only endogenous hydrogen from wood was consumed, and the reaction was performed using green solvents.

    Nyckelord
    Biomass, Lignin Green, Chemistry, Palladium, catalysis
    Nationell ämneskategori
    Organisk kemi
    Forskningsämne
    Kemi med inriktning mot organisk kemi
    Identifikatorer
    urn:nbn:se:uu:diva-226637 (URN)10.1002/cssc.201402017 (DOI)000340519500016 ()
    Forskningsfinansiär
    Energimyndigheten
    Tillgänglig från: 2014-06-18 Skapad: 2014-06-18 Senast uppdaterad: 2017-12-05Bibliografiskt granskad
  • 3.
    Galkin, Maxim
    et al.
    Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för kemi - BMC, Syntetisk organisk kemi.
    Samec, Joseph
    Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för kemi - BMC, Syntetisk organisk kemi.
    Selective Route to 2-Propenyl Aryls Directly from Wood by a Tandem Organosolv and Palladium-Catalysed Transfer Hydrogenolysis2014Ingår i: ChemSusChem, ISSN 1864-5631, E-ISSN 1864-564X, Vol. 7, nr 8, s. 2154-2158Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    A tandem organosolv pulping and Pd-catalysed transfer hydrogenolysis depolymerisation and deoxygenation has been developed. The tandem process generated 2-methoxy-4-(prop-1-enyl)phenol in 23 % yield (92 % theoretical monomer yield) starting from pine wood and 2,6-dimethoxy-4-(prop-1-enyl)phenol in 49 % yield (92 % theoretical monomer yield) starting from birch wood. Only endogenous hydrogen from wood was consumed, and the reaction was performed using green solvents.

  • 4.
    Galkin, Maxim V.
    et al.
    Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för kemi - BMC.
    Dahlstrand, Christian
    Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för kemi - BMC.
    Samec, Joseph S. M.
    Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för kemi - BMC.
    Mild and Robust Redox-Neutral Pd/C-Catalyzed Lignol -O-4 Bond Cleavage Through a Low-Energy-Barrier Pathway2015Ingår i: ChemSusChem, ISSN 1864-5631, E-ISSN 1864-564X, Vol. 8, nr 13, s. 2187-2192Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    A Pd/C catalyzed redox neutral CO bond cleavage of 2-aryloxy-1-arylethanols has been developed. The reactions are carried out at 80 degrees C, in air, using a green solvent system to yield the aryl ketones in near quantitative yields. Addition of catalytic amounts of a hydrogen source to the reaction mixture activates the catalyst to proceed through a low energy barrier pathway. Initial studies support a transfer hydrogenolysis reaction mechanism that proceeds through an initial dehydrogenation followed by an enol adsorption to Pd/C and a reductive CO bond cleavage.

  • 5.
    Galkin, Maxim V.
    et al.
    Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för kemi - BMC, Syntetisk organisk kemi.
    Sawadjoon, Supaporn
    Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för kemi - BMC, Syntetisk organisk kemi.
    Rohde, Volker
    Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för kemi - BMC, Syntetisk organisk kemi.
    Dawange, Monali
    Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för kemi - BMC, Syntetisk organisk kemi.
    Samec, Joseph S. M.
    Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för kemi - BMC, Syntetisk organisk kemi.
    Mild Heterogeneous Palladium-Catalyzed Cleavage of beta-O-4 '-Ether Linkages of Lignin Model Compounds and Native Lignin in Air2014Ingår i: ChemCatChem, ISSN 1867-3880, E-ISSN 1867-3899, Vol. 6, nr 1, s. 179-184Artikel i tidskrift (Refereegranskat)
    Abstract [en]

    A mild and robust heterogeneous palladium-catalyzed CO bond cleavage of 2-aryloxy-1-arylethanols using formic acid as reducing agent in air was developed. The cleaved products were isolated in 92-98% yield; and by slightly varying the reaction conditions, a ketone, an alcohol, or an alkane can be generated in near-quantitative yield. This reaction is applicable to cleaving the -O-4-ether bond found in lignin polymers of different origin. The reaction was performed on a lignin polymer model to generate either the monomeric aryl ketone or alkane in a quantitative yield. Moderate depolymerization was achieved with native lignin at similar reaction conditions. Mechanistic studies under kinetic control indicate that an initial palladium-catalyzed dehydrogenation of the alcohol is followed by insertion of palladium to an enol equivalent. A palladium-formato complex reductively cleaves the palladium-enolate complex to generate the ketone.

  • 6.
    Sawadjoon, Supaporn
    et al.
    Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för kemi - BMC, Syntetisk organisk kemi.
    Galkin, Maxim
    Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för kemi - BMC, Syntetisk organisk kemi.
    Dahlstrand, Christian
    Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för kemi - BMC.
    Rohde, Volker
    Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för kemi - BMC.
    Samec, Joseph S. M.
    Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för kemi - BMC, Syntetisk organisk kemi.
    Selective palladium-catalyzed reductive cleavage of beta-O-4-glucolaryl ether linkages in lignin model compounds2013Ingår i: Abstract of Papers of the American Chemical Society, ISSN 0065-7727, Vol. 245, s. 15-ORGN-Artikel i tidskrift (Övrigt vetenskapligt)
1 - 6 av 6
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