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  • 1. Gabrielsson, Erik
    et al.
    Tian, Haining
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Eriksson, Susanna K.
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Gao, Jiajia
    Chen, Hong
    Li, Fusheng
    Oscarsson, Johan
    Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy, Molecular and condensed matter physics.
    Sun, Junliang
    Rensmo, Håkan
    Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy, Molecular and condensed matter physics.
    Kloo, Lars
    Hagfeldt, Anders
    Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
    Sun, Licheng
    Dipicolinic acid: a strong anchoring group with tunable redox and spectral behavior for stable dye-sensitized solar cells2015In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 51, no 18, p. 3858-3861Article in journal (Refereed)
    Abstract [en]

    Dipicolinic acidwas investigated as a new anchoring group for DSSCs. A pilot dye (PD2) bearing this new anchoring group was found to adsorb significantly stronger to TiO2 than its cyanoacrylic acid analogue. The electrolyte composition was found to have a strong effect on the photoelectrochemical properties of the adsorbed dye in the device, allowing the dye LUMO energy to be tuned by 0.5 eV. Using a pyridine-free electrolyte, panchromatic absorption of the dye on TiO2 extending to 900 nm has been achieved. Solar cells using PD2 and a Co(bpy)(3) based electrolyte showed unique stability under simulated sunlight and elevated temperatures.

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