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2024 (English)In: Atmospheric Chemistry And Physics, ISSN 1680-7316, E-ISSN 1680-7324, Vol. 24, no 3, p. 1895-1918Article in journal (Refereed) Published
Abstract [en]
To compare in situ and laboratory estimates of sea spray aerosol (SSA) production fluxes, we conducted two research campaigns in the vicinity of an eddy covariance (EC) flux tower on the island of ostergarnsholm in the Baltic Sea during May and August 2021. To accomplish this, we performed EC flux measurements for particles with diameters between 0.25 and 2.5 mu m simultaneously with laboratory measurements using a plunging jet sea spray simulation chamber containing local seawater sampled close to the footprint of the flux tower. We observed a log-linear relationship between wind speed and EC-derived SSA emission fluxes, a power-law relationship between significant wave height and EC-derived SSA emission fluxes, and a linear relationship between wave Reynolds number and EC-derived SSA emission fluxes, all of which are consistent with earlier studies. Although we observed a weak negative relationship between particle production in the sea spray simulation chamber and seawater chlorophyll-alpha concentration and a weak positive relationship with the concentration of fluorescent dissolved organic matter in seawater, we did not observe any significant impact of dissolved oxygen on particle production in the chamber.To obtain an estimate of the size-resolved emission spectrum for particles with dry diameters between 0.015 and 10 mu m, we combined the estimates of SSA particle production fluxes obtained using the EC measurements and the chamber measurements in three different ways: (1) using the traditional continuous whitecap method, (2) using air entrainment measurements, and (3) simply scaling the chamber data to the EC fluxes. In doing so, we observed that the magnitude of the EC-derived emission fluxes compared relatively well to the magnitude of the fluxes obtained using the chamber air entrainment method as well as the previous flux measurements of and the parameterizations of and . As a result of these measurements, we have derived a wind-speed-dependent and wave-state-dependent SSA parameterization for particles with dry diameters between 0.015 and 10 mu m for low-salinity waters such as the Baltic Sea, thus providing a more accurate estimation of SSA production fluxes.
Place, publisher, year, edition, pages
Copernicus Publications, 2024
National Category
Meteorology and Atmospheric Sciences
Identifiers
urn:nbn:se:uu:diva-529828 (URN)10.5194/acp-24-1895-2024 (DOI)001189714400001 ()
Funder
Swedish Research Council, 2018-04255Swedish Research Council Formas, 2007-1362Swedish Research Council
2024-06-102024-06-102025-02-07Bibliographically approved