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2026 (English) In: Acta Materialia, ISSN 1359-6454, E-ISSN 1873-2453, Vol. 313, article id 122273Article in journal (Refereed) Published
Abstract [en] We report a comprehensive study of the temperature-dependent structural, magnetic, vibrational, and dielectric properties of Al-substituted M-type hexaferrites SrFe12-x AlxO19 . Neutron powder diffraction and Mössbauer spectrometry show that Al3+ preferentially replaces Fe3+ at spin-up octahedral sites (2a , 12k ), disrupting the exchange coupling with the spin-down 4f tetrahedral sites and leading to a progressive reduction of site-specific magnetic moments and a systematic decrease in the Curie temperature, supported by temperature-dependent susceptibility measurements. Raman spectroscopy reveals pronounced phonon anomalies near TC , particularly in modes associated with bipyramidal Fe-O vibrations, reflecting the weakening of both 4e-12k and 4e -4f exchange pathways. However, the coercive field exhibits a dramatic increase, reaching μ0 HC ∼1.2 T for SrFe9.6 Al2.4 O19 , among the largest values reported for this class. Susceptibility measurements suggest that Al substitution, while weakening the superexchange network, contributes to the stabilization of single-domain behavior.
Place, publisher, year, edition, pages
Elsevier, 2026
Keywords Chemical structure, Magnetic properties, Neutron diffraction, Raman spectroscopy, Nanoparticles
National Category
Condensed Matter Physics Physical Chemistry Inorganic Chemistry
Identifiers urn:nbn:se:uu:diva-587566 (URN) 10.1016/j.actamat.2026.122273 (DOI) 001767728400001 () 2-s2.0-105037866205 (Scopus ID)
Funder Swedish Energy Agency, 46561-1Swedish Energy Agency, 50667-1Olle Engkvists stiftelse, 224–0046EU, Horizon 2020, 823717
2026-06-022026-06-022026-06-02 Bibliographically approved