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A Valleytronic Diamond Transistor: Electrostatic Control of Valley Currents and Charge-State Manipulation of NV Centers
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Electrical Engineering, Electricity. (Diamond electronics)ORCID iD: 0000-0002-8815-5992
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Electrical Engineering, Electricity.ORCID iD: 0000-0002-6057-7931
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Electrical Engineering, Electricity.ORCID iD: 0000-0002-6402-9393
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Electrical Engineering, Electricity. Center for Nanoscale Materials, Argonne National Laboratory, Argonne, Illinois 60439, United States.ORCID iD: 0000-0003-0669-9476
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2021 (English)In: Nano letters (Print), ISSN 1530-6984, E-ISSN 1530-6992, Vol. 21, no 1, p. 868-874Article in journal (Refereed) Published
Abstract [en]

The valley degree of freedom in many-valley semiconductors provides a new paradigm for storing and processing information in valleytronic and quantum-computing applications. Achieving practical devices requires all-electric control of long-lived valley-polarized states, without the use of strong external magnetic fields. Because of the extreme strength of the carbon–carbon bond, diamond possesses exceptionally stable valley states that provide a useful platform for valleytronic devices. Using ultrapure single-crystalline diamond, we demonstrate electrostatic control of valley currents in a dual-gate field-effect transistor, where the electrons are generated with a short ultraviolet pulse. The charge current and the valley current measured at the receiving electrodes are controlled separately by varying the gate voltages. We propose a model to interpret experimental data, based on drift-diffusion equations coupled through rate terms, with the rates computed by microscopic Monte Carlo simulations. As an application, we demonstrate valley-current charge-state modulation of nitrogen-vacancy centers.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2021. Vol. 21, no 1, p. 868-874
Keywords [en]
diamond, valleytronics, pseudospin, nitrogen-vacancy center, valley transistor
National Category
Electrical Engineering, Electronic Engineering, Information Engineering
Research subject
Engineering Science with specialization in Science of Electricity
Identifiers
URN: urn:nbn:se:uu:diva-434119DOI: 10.1021/acs.nanolett.0c04712ISI: 000611082000117PubMedID: 33337898OAI: oai:DiVA.org:uu-434119DiVA, id: diva2:1525979
Funder
Swedish Research Council, 2018-04154ÅForsk (Ångpanneföreningen's Foundation for Research and Development), 15-288ÅForsk (Ångpanneföreningen's Foundation for Research and Development), 19-427Stiftelsen Olle Engkvist Byggmästare, 198-0384StandUpSwedish National Infrastructure for Computing (SNIC)Available from: 2021-02-05 Created: 2021-02-05 Last updated: 2024-01-15Bibliographically approved
In thesis
1. Low Temperature Charge Transport in Diamond
Open this publication in new window or tab >>Low Temperature Charge Transport in Diamond
2023 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

Diamond is a wide band semiconductor with fascinating electrical and physical properties. It has high thermal and electrical conductivity, high electrical breakdown field, high radiation hardness and is chemically inert. These properties make diamond an excellent material for high power electronics, high frequency electronics, particle detectors and for electronics in hazardous environments. Moreover, diamond has been suggested for applications in valleytronics.

Valleytronics is a term for semiconductor technology that exploits minima in an energy band, so called valleys. In diamond there are six of these valleys in the conduction band and the conduction electrons resides in one of these six valleys at low temperatures. The valley an electron is in, its valley polarization, affects how it behaves in an electric field. The valley polarization along with an understanding of the electron-phonon scattering processes makes a good framework for understanding of electron transport in diamond. In this thesis, both of these topics have been explored, with the purpose of understanding low temperature electron transport in diamond. A detailed description of low temperature charge transport is relevant for several reasons. Firstly, it can help with understanding the charge transport in e.g. detectors. Secondly, it gives more degrees of freedom when designing new electronics.   

In this thesis, both experiments and simulations has been used investigate low temperature transport in diamond. The main experiment method used was time-of-flight were the drift current of valley polarized electrons measured between two contacts. These experiment could then be compared with Monte Carlo simulations. The simulations gave valuable insigne into the dynamics of the electrons. This self-written code for Monte Carlo simulations is described in greater detail in this thesis. 

Some highlighted results of this thesis are as follows: optical observations of valley polarized diffusion, electrical control of valley polarized currents and the estimations of the acoustic deformation potentials to Du = 18.5 eV and Dd = -5.7 eV. This thesis also includes a more general part about charge transport.

Place, publisher, year, edition, pages
Uppsala: Acta Universitatis Upsaliensis, 2023. p. 100
Series
Digital Comprehensive Summaries of Uppsala Dissertations from the Faculty of Science and Technology, ISSN 1651-6214 ; 2273
National Category
Other Electrical Engineering, Electronic Engineering, Information Engineering
Research subject
Engineering Science with specialization in Electronics
Identifiers
urn:nbn:se:uu:diva-500810 (URN)978-91-513-1820-2 (ISBN)
Public defence
2023-06-08, Polhemsalen, Lägerhyddsvägen 1, Uppsala, 09:15 (English)
Opponent
Supervisors
Available from: 2023-05-15 Created: 2023-04-25 Last updated: 2024-01-18

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Suntornwipat, NattakarnMajdi, SamanGabrysch, MarkusKumar Kovi, KiranDjurberg, ViktorIsberg, Jan

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