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Crossover From Individual to Collective Magnetism in Dense Nanoparticle Systems: Local Anisotropy Versus Dipolar Interactions
Univ Castilla La Mancha, Inst Reg Invest Cient Aplicada IRICA, Ciudad Real 13071, Spain.;Univ Castilla La Mancha, Dept Fis Aplicada, Ciudad Real 13071, Spain..ORCID iD: 0000-0001-5737-0035
Inst Nanosci & Nanotechnol NCSR Demokritos, Aghia Paraskevi 15310, Greece..
Inst Mat Res & Engn, NanoBio Lab, 31 Biopolis Way,09-01, Singapore 138669, Singapore..
Univ Castilla La Mancha, Inst Reg Invest Cient Aplicada IRICA, Ciudad Real 13071, Spain.;Univ Castilla La Mancha, Dept Fis Aplicada, Ciudad Real 13071, Spain..
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2022 (English)In: Small, ISSN 1613-6810, E-ISSN 1613-6829, Vol. 18, no 28, article id 2106762Article in journal (Refereed) Published
Abstract [en]

Dense systems of magnetic nanoparticles may exhibit dipolar collective behavior. However, two fundamental questions remain unsolved: i) whether the transition temperature may be affected by the particle anisotropy or it is essentially determined by the intensity of the interparticle dipolar interactions, and ii) what is the minimum ratio of dipole-dipole interaction (E-dd) to nanoparticle anisotropy (KefV, anisotropy.volume) energies necessary to crossover from individual to collective behavior. A series of particle assemblies with similarly intense dipolar interactions but widely varying anisotropy is studied. The K-ef is tuned through different degrees of cobalt-doping in maghemite nanoparticles, resulting in a variation of nearly an order of magnitude. All the bare particle compacts display collective behavior, except the one made with the highest anisotropy particles, which presents "marginal" features. Thus, a threshold of KefV/E-dd approximate to 130 to suppress collective behavior is derived, in good agreement with Monte Carlo simulations. This translates into a crossover value of approximate to 1.7 for the easily accessible parameter T-MAX(interacting)/T-MAX(non-interacting) (ratio of the peak temperatures of the zero-field-cooled magnetization curves of interacting and dilute particle systems), which is successfully tested against the literature to predict the individual-like/collective behavior of any given interacting particle assembly comprising relatively uniform particles.

Place, publisher, year, edition, pages
Wiley-VCH Verlagsgesellschaft, 2022. Vol. 18, no 28, article id 2106762
Keywords [en]
dipolar interactions, magnetic anisotropy, magnetic nanoparticles, superspin glass
National Category
Condensed Matter Physics
Identifiers
URN: urn:nbn:se:uu:diva-485651DOI: 10.1002/smll.202106762ISI: 000809267600001PubMedID: 35689307OAI: oai:DiVA.org:uu-485651DiVA, id: diva2:1701099
Funder
EU, Horizon 2020, 101046909Swedish Research CouncilAvailable from: 2022-10-04 Created: 2022-10-04 Last updated: 2022-10-04Bibliographically approved

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Andersson, MikaelMathieu, RolandNordblad, Per

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