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The present study combines Radio and Plasma Wave Science/Langmuir Probe and Ion and Neutral Mass Spectrometer data from Cassini's last four orbits into Saturn's lower ionosphere to constrain the effective recombination coefficient α₃₀₀ from measured number densities and electron temperatures at a reference electron temperature of 300 K. Previous studies have shown an influx of ring material causes a state of electron depletion due to grain charging, which will subsequently affect the ionospheric chemistry. The requirement to take grain charging into account limits the derivation of α₃₀₀ to upper limits. Assuming photochemical equilibrium and using an established method to calculate the electron production rate, we derive upper limits for α₃₀₀ of ≲ 3 × 10⁻⁷ cm³ s⁻¹ for altitudes below 2000 km. This suggests that Saturn's ionospheric positive ions are dominated by species with low recombination rate coefficients like HCO⁺. An ionosphere dominated by water group ions or complex hydrocarbons, as previously suggested, is incompatible with this result, as these species have recombination rate coefficients > 5 × 10⁻⁷ cm³ s⁻¹ at an electron temperature of 300 K.

We present a semianalytical photochemical model of Saturn's near-equatorial ionosphere and adapt it to two regions (similar to 2200 and similar to 1700 km above the 1 bar level) probed during the inbound portion of Cassini's orbit 292 (2017 September 9). The model uses as input the measured concentrations of molecular hydrogen, hydrogen ion species, and free electrons, as well as the measured electron temperature. The output includes upper limits, or constraints, on the mixing ratios of two families of molecules, on ion concentrations, and on the attachment rates of electrons and ions onto dust grains. The model suggests mixing ratios of the two molecular families that, particularly near similar to 1700 km, differ notably from what independent measurements by the Ion Neutral Mass Spectrometer suggest. Possibly connected to this, the model suggests an electron-depleted plasma with a level of electron depletion of around 50%. This is in qualitative agreement with interpretations of Radio Plasma Wave Science/Langmuir Probe measurements, but an additional conundrum arises in the fact that a coherent photochemical equilibrium scenario then relies on a dust component with typical grain radii smaller than 3 angstrom.

For orbits 288 and 292 of Cassini's Grand Finale, clear dips (sharp and narrow decreases) are visible in the H-2(+) densities measured by the Ion and Neutral Mass Spectrometer (INMS). In 2017, the southern hemisphere of Saturn was shadowed by its rings and the substructures within. Tracing a path of the solar photons through the ring plane to Cassini's position, we can identify regions in the ionosphere that were shadowed by the individual ringlets and plateaus (with increased optical depths) of Saturn's C ring. The calculated shadowed altitudes along Cassini's trajectory line up well with the dips in the H-2(+) data when adjusting the latter based on a detected evolving shift in the INMS timestamps since 2013, illustrating the potential for verification of instrument timings. We can further estimate the mean optical depths of the ringlets/plateaus by comparing the dips to inbound H-2(+) densities. Our results agree well with values derived from stellar occultation measurements. No clear dips are visible for orbits 283 and 287, whose periapsides were at higher altitudes. This can be attributed to the much longer chemical lifetime of H2+ at these higher altitudes, which in turn can be further used to estimate a lower limit for the flow speed along Cassini's trajectory. The resulting estimate of similar to 0.3 km s(-1) at an altitude of similar to 3400 km is in line with prior suggestions. Finally, the ringlet and plateau shadows are not associated with obvious dips in the electron density, which is expected due to their comparatively long chemical (recombination) lifetime.

A surprisingly strong influx of organic-rich material into Saturn's upper atmosphere from its rings was observed during the proximal obits of the Grand Finale of the Cassini mission. Measurements by the Ion and Neutral Mass Spectrometer (INMS) gave insights into the composition of the material, but it remains to be resolved what fraction of the inferred heavy volatiles should be attributed as originating from the fragmentation of dust particles in the instrument versus natural ablation of grains in the atmosphere. In the present study, we utilize measured light ion and neutral densities to further constrain the abundances of heavy volatiles in Saturn's ionosphere through a steady-state model focusing on helium ion chemistry. We first show that the principal loss mechanism of He+ in Saturn's equatorial ionosphere is through reactions with species other than H-2. Based on the assumption of photochemical equilibrium at altitudes below 2,500 km, we then proceed by estimating the mixing ratio of heavier volatiles down to the closest approaches for Cassini's proximal orbits 288 and 292. Our derived mixing ratios for the inbound part of both orbits fall below those reported from direct measurements by the INMS, with values of similar to 2 x 10(-4) at closest approaches and order-of-magnitude variations in either direction over the orbits. This aligns with previous suggestions that a large fraction of the neutrals measured by the INMS stems from the fragmentation of infalling dust particles that do not significantly ablate in the considered part of Saturn's atmosphere and are thus unavailable for reactions. Plain Language Summary During the final orbits of the Cassini mission, the spacecraft flew between Saturn's rings and the planets upper atmosphere. The onboard plasma instruments detected a large amount of ring particles falling toward the planet, but direct measurements of the composition of these grains are complicated due to the high spacecraft speed and instrumental effects. In this study, we present an independent method to estimate the abundance of heavier neutral species entering the atmosphere from infalling ring material. This method relies on helium ion chemistry and the measured light ion and neutral densities. Our results generally fall below those inferred from direct measurements. Together with comparisons to other studies, this potentially suggests that a large fraction of the infalling neutral species do not significantly ablate in the considered part of Saturn's atmosphere (and remain bound to the dust grains instead) and are thus unavailable for reactions.