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Probing spin waves in Co3O4 nanoparticles for magnonics applications
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Materials Science and Engineering, Solid State Physics. European Spallat Source ERIC, SE-22363 Lund, Sweden; Forschungszentrum Julich, Julich Ctr Neutron Sci JCNS 1, D-52425 Julich, Germany.ORCID iD: 0000-0002-0316-3265
Peking Univ, Sch Adv Mat, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China..
Peking Univ, Sch Adv Mat, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China..ORCID iD: 0000-0001-9306-908X
Worcester Polytech Inst, Dept Chem Engn, Worcester, MA 01609 USA..ORCID iD: 0000-0001-9547-7175
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2024 (English)In: Nanoscale, ISSN 2040-3364, E-ISSN 2040-3372, Vol. 16, no 3, p. 1291-1303Article in journal (Refereed) Published
Abstract [en]

The magnetic properties of spinel nanoparticles can be controlled by synthesizing particles of a specific shape and size. The synthesized nanorods, nanodots and cubic nanoparticles have different crystal planes selectively exposed on the surface. The surface effects on the static magnetic properties are well documented, while their influence on spin waves dispersion is still being debated. Our ability to manipulate spin waves using surface and defect engineering in magnetic nanoparticles is the key to designing magnonic devices. We synthesized cubic and spherical nanoparticles of a classical antiferromagnetic material Co3O4 to study the shape and size effects on their static and dynamic magnetic proprieties. Using a combination of experimental methods, we probed the magnetic and crystal structures of our samples and directly measured spin wave dispersions using inelastic neutron scattering. We found a weak, but unquestionable, increase in exchange interactions for the cubic nanoparticles as compared to spherical nanoparticle and bulk powder reference samples. Interestingly, the exchange interactions in spherical nanoparticles have bulk-like properties, despite a ferromagnetic contribution from canted surface spins.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2024. Vol. 16, no 3, p. 1291-1303
National Category
Condensed Matter Physics Inorganic Chemistry
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URN: urn:nbn:se:uu:diva-522739DOI: 10.1039/d3nr04424fISI: 001129107200001PubMedID: 38131194OAI: oai:DiVA.org:uu-522739DiVA, id: diva2:1836371
Funder
Swedish Research Council, 2016-06959Swedish Research Council, 2019-00207Available from: 2024-02-08 Created: 2024-02-08 Last updated: 2024-02-08Bibliographically approved

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Feygenson, MikhailSalazar-Alvarez, GermánUlusoy, SedaValvo, Mario

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Feygenson, MikhailXiao, YinguoTeng, XiaoweiPodlesnyak, Andrey A.Salazar-Alvarez, GermánUlusoy, SedaValvo, Mario
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